Characterization and Optical Properties of MnO Doped CuO-Containing Phosphate Glass as Absorption Filters
DOI:
https://doi.org/10.24297/jap.v15i0.7923Keywords:
Phosphate glass – Manganese – bandpass filter – Transition metals – Refractive indexAbstract
In order to demonstrate the intrinsic and extrinsic changes induced by MnO in the phosphate glass network, a glass system of composition 44P2O5-38ZnO-2CuO-(16-x)Na2O-xMnO (where, x = 1, 2, 3, 4, and 5 mol%) was prepared using the conventional melt quenching technique. XRD patterns confirmed the non-crystalline nature of the prepared samples. The density and molar volume as a function of MnO content were determined to characterize structure of the obtained glasses. The optical spectroscopic studies of the prepared samples were carried out over (190-1000 nm) spectral range. The prepared samples were found to behave as bandpass filters in the visible region of spectrum. The UV cutoff wavelength was shifted from 308 nm to 352 nm by increasing content of MnO which is very useful in the optical technology requirements such as ultraviolet preventing applications and the protection from UV-LASER. The optical band gap was decreased by increasing content of MnO whilst, the Urbach energy was increased. The decrease in optical band gap was attributed to the progressive increase in non-bridging oxygens (NBOs) concentration with the addition of MnO. The refractive index was found to be enhanced with the addition of MnO by the effect of increase in overall polarizability. However, the optical polarizability was found to be correlated to the chemical composition of the glass. The results reveal the role of MnO as a network modifier in the phosphate glass matrix.
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N.P. Bansal and R.H. Doremus, “Handbook of Glass Properties”, Academic Press, 1986.
J.H. Campbell, J.S. Hayden and A. Marker, “High-power solid-state lasers: a laser glass perspective”, Int. J. Appl. Glass Sci., vol. 2, pp. 3-29, 2011.
J.S. Fernandes, P. Gentile, R.A. Pires, R.L. Reis and P.V. Hatton, “Multifunctional bioactive glass and glass-ceramic biomaterials with antibacterial properties for repair and regeneration of bone tissue”, Acta Biomater., vol. 59, pp. 2-11, 2017.
R.K. Brow, “Review: the structure of simple phosphate glasses”, J. Non-Cryst. Solids, vol. 263-264, pp.1-28, 2000.
P. Pascuta, G. Borodi, N. Jumate, I. Vida-Simiti, D. Viorel and E. Culea, “The structural role of manganese ions in some zinc phosphate glasses and glass ceramics” J. Alloy. Compd., vol. 504, pp. 479-483, 2010.
B.P. Choudhary and N.B. Singh, “Properties of silver phosphate glass in the presence of nanosize cobalt and nickel oxides”, J. Non-Cryst. Solids, vol. 440, pp. 59-69, 2016.
H.A. Abd El-Ghany, “Development of a New Glass for Both Visible and Near-Infrared Optical Applications” Key Eng. Mater., vol. 786, pp. 224-235, 2018.
B.P. Choudhary, S. Rai and N.B. Singh, “Properties of silver phosphate glass doped with nanosize zinc oxide”, Ceram. Int., vol. 42, pp. 10813-10825, 2016.
S. Li, Y. Lu, Y. Qu, Y. Xu, L. Ming, Z. Song and Y. Yue, “Influences of ZnO on the chemical durability and thermal stability of calcium iron phosphate glasses”, J. Non-Cryst. Solids, vol. 498, pp. 228-235, 2018.
G. Murali Krishna, Y. Gandhi, N. Venkatramaiah, R. Venkatesan and N. Veeraiah, “Features of the local structural disorder in Li2O-CaF2-P2O5 glass-ceramics with Cr2O3 as nucleating agent”, Physica B, vol. 403, pp. 702-710, 2008.
M. Altaf and M.A. Chaudhry, “Physical Properties of Lithium Containing Cadmium Phosphate Glasses”, J. Mod. Phys., vol. 1, pp. 201-205, 2010.
C. Ivascu, I.B. Cozar, L. Daraban and G. Damian, “Spectroscopic investigation of P2O5-CdO-Li2O glass system”, J. Non-Cryst. Solids, vol. 359, pp. 60-64, 2013.
Y.M. Moustofa, K. El-Egili, “Infrared spectra of sodium phosphate glasses”, J. Non-Cryst. Solids, vol. 240, pp. 144-153, 1998.
11. M. Altaf, M.A. Chaudhry. "Physical properties of sodium cadmium phosphate glasses" Inter. J. Modern Phys. B, vol. 25, pp. 3503-3512, 2011.
R.K. Brow, D.R. Tallant, S.T. Myers and C.C. Phifer, “The short-range structure of zinc polyphosphate glass”, J. Non-Cryst. Solids, vol. 191, pp. 45-55, 1995.
K. Suzuya, K. Itoh, A. Kajinami and C.K. Loong, “The structure of binary zinc phosphate glasses”, J. Non-Cryst. Solids, vol. 345-346, pp. 80-87, 2004.
M. Ahmad, F. Salman, M. Morsi, K. El-Badry and F. Metwall, “Electrical Properties of Some Copper-Containing Phosphate Glasses”, J. Mater. Sci., vol. 41, pp.1667-1669, 2006.
N.K. Mohan, M.R. Reddy, C.K. Jayasankar and N. Veeraiah, “Spectroscopic and dielectric studies on MnO doped PbO–Nb2O5–P2O5 glass system”, J. Alloy. Comp., vol. 458, pp. 66-76, 2008.
X. Li, A. Lu and H. Yang, “Structure of ZnO–Fe2O3–P2O5 glasses probed by Raman and IR spectroscopy”, J. Non-Cryst. Solids, vol. 389, pp. 21-27, 2014.
G. Broglia, C. Mugoni, C. Siligardi and M. Montorsi, “Lithium and copper transport properties in phosphate glasses: A Molecular Dynamics study, J. Non-Cryst. Solids, vol. 481, pp. 522-529, 2018.
D.A. Magdas, R. Stefan, D. Toloman and N.S. Vedeanu, “Copper ions influence on lead–phosphate glass network”, J. Mol. Struct., vol. 1056-1057, pp. 314-318, 2014.
H. Elhaes, M. Attallah, Y. Elbashar, M. El-Okr, M. Ibrahim, “Application of Cu2O-doped phosphate glasses for bandpass filter” Physica B: Cond. Matt., vol. 449, pp. 251-254, 2014.
P. Pascuta, M. Bosca, G. Borodi and E. Culea, “Thermal, structural and magnetic properties of some zinc phosphate glasses doped with manganese ions”, J. Alloy. Compd., vol. 509, pp. 4314-4319, 2011.
W. Ahmina, M. El Moudane, M. Zriouil and M. Taibi, “Glass-forming region, structure and some properties of potassium manganese phosphate glasses”, Phase Transit., vol. 89, pp. 1-11, 2016
S.S. Sastry and B.R. Rao, “Spectroscopic characterization of manganese-doped alkaline earth lead zinc phosphate glasses”, Bull. Mater. Sci., vol. 38, pp. 475-482, 2015.
Y.H. Elbashar, H.A. Abd El-Ghany, “Optical spectroscopic analysis of Fe2O3 doped CuO containing phosphate glass”, Opt. Quant. Electron. 49:310, pp. 1-13, 2017.
H. Abd El-Ghany, “Cadmium Doped Copper Containing Phosphate Glass as a Bandpass Filter for Solar Cell Protection”, J. Adv. Phys., vol. 14, pp. 5488-5503, 2018.
N. Aboulfotoh, Y. Elbashar, M. Ibrahem, M. Elokr, “Characterization of copper doped phosphate glasses for optical applications” Ceram. Int., vol. 40, pp.10395-10399, 2014.
R.O. Omrani, S. Krimi, J.J. Videau, I. Khattech, A. El Jazouli and M. Jemal, “Structural investigations and calorimetric dissolution of manganese phosphate glasses”, J. Non-Cryst. Solids, vol. 389, pp. 66-71, 2014.
A.S. Rao, Y.N. Ahammed, R.R. Reddy, T.V.R. Rao, “Spectroscopic studies of Nd3+-doped alkali fluoroborophosphate glasses”, Opt. Mater., vol. 10, pp. 245-252, 1998.
M.M. Ahmed, C.A. Hogarth and M.N. Khan, “A study of the electrical and optical properties of the GeO2-TeO2 glass system”, J. Mater. Sci. Lett., vol. 19, pp. 4040-4044, 1984.
Ch. Tirupataiah, T. Narendrudu, S. Suresh, P. Srinivasa Rao, P.M. Vinaya Teja, M.V. Sambasiva Rao, G. Chinna Ram and D. Krishna Rao, “Influence of valence state of copper ions on structural and spectroscopic properties of multi-component PbO-Al2O3-TeO2-GeO2-SiO2 glass ceramic system- a possible material for memory switching devices”, Opt. Mater., vol. 73, pp. 7-15, 2017.
Y.H. Elbashar • M.M. Rashad and D. A. Rayan, “Protection Glass Eyewear Against a YAG Laser Based on a Bandpass Absorption Filter”, Silicon 9, pp. 111-116, 2017.
K. Subrahmanyam, M. Salagram, “Optical band gap studies on (55 – x)Na2O – xPbO – 45P2O5 (SLP) glass system” Opt. Mater., vol. 15, pp. 181-186, 2000.
S.F. Khor, Z.A. Talib, F. Malek and E.M. Cheng, “Optical properties of ultraphosphate glasses containing mixed divalent zinc and magnesium ions” Opt. Mater., vol. 35, pp. 629-633, 2013.
A.K. Sandhu, S. Singh and O.P. Pandey, “Neutron irradiation effects on optical and structural properties of silicate glasses” Mater. Chem. Phys., vol. 115, pp. 783-788, 2009.
A.H. Khafagy, A.A. El-Adawy, A.A. Higazy, S. El-Rabaie, A.S. Eid, “Studies of some mechanical and optical properties of: (70 x)TeO2 + 15B2O3 + 15P2O5 + xLi2O glasses”, J. Non-Cryst. Solids 354, pp. 3152-3158, 2008.
Y. Wang, S. Dai, F. Chen, T. Xu and Q. Nie, “Physical properties and optical band gap of new tellurite glasses within the TeO2–Nb2O5–Bi2O3 system”, Mater. Chem. Phys., vol. 113, pp. 407-411, 2009.
V. Dimitrov and S. Sakka, “Linear and nonlinear optical properties of simple oxides. II”, J. Appl. Phys., vol. 79, pp. 1741-1745, 1996.
D.C. Ghosh and R. Biswas, “Theoretical Calculation of Absolute Radii of Atoms and Ions. Part 2. The Ionic Radii”, Int. J. Mol. Sci., vol. 4, pp. 379-407, 2003.
H. Ticha, J. Schwarz, L. Tichy and R. Mertens, “Physical Properties of PbO-ZnO-P2O5 Glasses II. Refractive Index and Optical Properties”, J. Optoelectron. Adv. Mater., vol. 6, pp. 747-753, 2004.
V. Dimitrov and T. Komatsu, “Classification of Simple Oxides: A Polarizability Approach”, J. Solid State Chem., vol. 163, pp. 100-112, 2002.
A. Klinokowski, “Non-Monotonic Variations of Some Parameters in Vitreous R2O-SiO2 and R2O-Al2O3-SiO2 Systems”, J. Non-Cryst. Solids, vol. 72, pp. 117-137, 1985.
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