Synthesis, crystal structure and spectroscopic characterization of a new organic bismuthate (III) [C9H28N4][Bi2Cl10].H2O
DOI:
https://doi.org/10.24297/jac.v9i2.5571Keywords:
Organic-inorganic hybrid material, Halogenobismuthates (III), Crystal structure, X-ray diffraction, IR spectroscopy, Raman spectroscopy.Abstract
The chemical preparation, crystal structure and spectroscopic characterization of [C9H28N4][Bi2Cl10].H2O have been reported. This compound crystallizes in the monoclinic system in space group P21/c and cell parameters a = 12.2385 (6), b = 17.3062 (7), c = 13.0772 (6) Å, β = 104.475 (5)°, Z = 4 and V = 2681.9 (2) Å3. Its crystal structure has been determined and refined to R = 0.049, using 5848 independent reflections. The atomic arrangement can be described by an alternation of organic and inorganic layers. The inorganic layer built up of [Bi2Cl10]4– bioctahedra arranged in sandwich between the organic layer. The organic groups are interconnected by the water molecules through N-H…O(W) hydrogen bonds to form infinite zig-zag chains spreading along the b-axis. These Chains are themselves interconnected by means of the N–H…Cl hydrogen bonds originating from [Bi2Cl10]4– anions, to form a three-dimensional network. Intermolecular Cl…Cl interactions between adjacent dimeric [Bi2Cl10]4– anions have been observed. The compound was also characterized by FT-IR and Raman spectrscopies.Downloads
Download data is not yet available.
References
[1] F. Neve, O. Francescangeli, A. Crispini, Inorg. Chem. Acta 338 (2002) 51-58.
[2] R. Jakubas, L. Sobczyk, Phase Transitions 20 (1990) 163-193.
[3] B. Kulicka, R. Jakubas, B. Bednarska-Bolek, G. Bator, Z. Ciunik, J. Mol. Struct 792 (2006) 151-156.
[4] F. Lazzarini, Acta Cryst. C41 (1985) 1617-1649.
[5] R. Blachnik, B. Jaschinski, H. Reuter, G. Z. Kauster, Kristallogr. 212 (1997) 874.
[6] A. Z. Lipka, Naturforsch Teil B38 (1983) 1615.
[7] J. Lefebvre, P. Carpentier, R. Jakubas, Acta Crystallogr. B47 (1991) 228-234.
[8] A. Z. Lipka, Anorg. Allg. Chem. 469 (1980) 229.
[9] B. Blazic, F. Lazzarini, Acta Crystallogr. C41 (1985) 1619-1621.
[10] H. Ishihara, S. Dou, A. Weiss, B. Bunsenges, Phys. Chem. 95 (1991) 659.
[11] CrysAlisPro, Agilent Technologies, Version 1.171.36.28 (release 01-02-2013) CrysAlis171 .NET) (compiled Feb1 2013, 16, 14, 44).
[12] R. C. Clark, J. S. Reid, Acta Crystallogr, A51 (1995) 887-897.
[13] A. Altomare, M. C. Burla, M. Camalli, G. L. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori, R. Spagna, J. Appl Crystallogr. 32 (1999) 115-119.
[14] P. W. Betteridge, J. R. Carruthers, R. I. Cooper, K. Prout, D. J. Watkin, J. Appl. Crystallogr. 36 (1998) 1487.
[15] K. Brandenburg, DIAMOND. Version 2.1. Crystal Impact GbR, Bonn, Germany, 1998.
[16] J. Bernstein, R. E. Davis, L. Shimoni, N. L. Chang, Angew. Chem. Int. Ed.34 (1995) 1555-1573.
[17] P. Ciapala, R. Jakuba, G. Bator, J. Zaleski, A. Pietrazko, M. Drozd, J. Baran. J. Phys. Condens. Matter. 9 (1997) 627-645.
[18] I. Turel, L. Goli, P. Bukovec, M. Gubina, J. Inorg. Biochem. 71 (1998) 53-60.
[19] S. Chaabouni, S. kamoun,J. Jaud, J. Chem. Crystallogr.28 (1998) 209-212.
[20] M. Khelifi, I. Mkaouar, F. Hlel, A. Ben Salah, R. Zouari. Ionics 16 (2010) 709-715.
[21] V. R. Hathwar, S. M. Roopan, R. Subashini, F. N. Khan, T. N. G. Row, T. N. G. J. Chem. Sci. 122 (2010) 677-685.
[22] M. Belhouchet, M. Bahri, J. M. Savariault, T. Mhiri, Spectrochim. Acta A 61 (2005) 387-393.
[23] G. Hertzberg, Infrared and Raman Spectra of Polyatomic Molecules, Van Nostrand, New york, 1966.
[24] Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, 1986.
[2] R. Jakubas, L. Sobczyk, Phase Transitions 20 (1990) 163-193.
[3] B. Kulicka, R. Jakubas, B. Bednarska-Bolek, G. Bator, Z. Ciunik, J. Mol. Struct 792 (2006) 151-156.
[4] F. Lazzarini, Acta Cryst. C41 (1985) 1617-1649.
[5] R. Blachnik, B. Jaschinski, H. Reuter, G. Z. Kauster, Kristallogr. 212 (1997) 874.
[6] A. Z. Lipka, Naturforsch Teil B38 (1983) 1615.
[7] J. Lefebvre, P. Carpentier, R. Jakubas, Acta Crystallogr. B47 (1991) 228-234.
[8] A. Z. Lipka, Anorg. Allg. Chem. 469 (1980) 229.
[9] B. Blazic, F. Lazzarini, Acta Crystallogr. C41 (1985) 1619-1621.
[10] H. Ishihara, S. Dou, A. Weiss, B. Bunsenges, Phys. Chem. 95 (1991) 659.
[11] CrysAlisPro, Agilent Technologies, Version 1.171.36.28 (release 01-02-2013) CrysAlis171 .NET) (compiled Feb1 2013, 16, 14, 44).
[12] R. C. Clark, J. S. Reid, Acta Crystallogr, A51 (1995) 887-897.
[13] A. Altomare, M. C. Burla, M. Camalli, G. L. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori, R. Spagna, J. Appl Crystallogr. 32 (1999) 115-119.
[14] P. W. Betteridge, J. R. Carruthers, R. I. Cooper, K. Prout, D. J. Watkin, J. Appl. Crystallogr. 36 (1998) 1487.
[15] K. Brandenburg, DIAMOND. Version 2.1. Crystal Impact GbR, Bonn, Germany, 1998.
[16] J. Bernstein, R. E. Davis, L. Shimoni, N. L. Chang, Angew. Chem. Int. Ed.34 (1995) 1555-1573.
[17] P. Ciapala, R. Jakuba, G. Bator, J. Zaleski, A. Pietrazko, M. Drozd, J. Baran. J. Phys. Condens. Matter. 9 (1997) 627-645.
[18] I. Turel, L. Goli, P. Bukovec, M. Gubina, J. Inorg. Biochem. 71 (1998) 53-60.
[19] S. Chaabouni, S. kamoun,J. Jaud, J. Chem. Crystallogr.28 (1998) 209-212.
[20] M. Khelifi, I. Mkaouar, F. Hlel, A. Ben Salah, R. Zouari. Ionics 16 (2010) 709-715.
[21] V. R. Hathwar, S. M. Roopan, R. Subashini, F. N. Khan, T. N. G. Row, T. N. G. J. Chem. Sci. 122 (2010) 677-685.
[22] M. Belhouchet, M. Bahri, J. M. Savariault, T. Mhiri, Spectrochim. Acta A 61 (2005) 387-393.
[23] G. Hertzberg, Infrared and Raman Spectra of Polyatomic Molecules, Van Nostrand, New york, 1966.
[24] Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley-Interscience, 1986.
Downloads
Published
2014-05-02
How to Cite
Aloui, Z., Abid, S., Jeanneau, E., Rzaigui, M., & Ben Nasr, C. (2014). Synthesis, crystal structure and spectroscopic characterization of a new organic bismuthate (III) [C9H28N4][Bi2Cl10].H2O. JOURNAL OF ADVANCES IN CHEMISTRY, 9(2), 1911–1920. https://doi.org/10.24297/jac.v9i2.5571
Issue
Section
Articles
License
All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.
