Preparation and Characterization of bis (4-methoxyanilinium) tetrachlorozincate

Authors

  • H. Rahmouni Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna
  • W. Smirani Sta Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna
  • M. Rzaigui Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna

DOI:

https://doi.org/10.24297/jac.v10i3.2284

Keywords:

Organic-inorganic hybrid, Crystal structure, IR Spectroscopy.

Abstract

A new zinc complex of formula [C7H10NO]2 ZnCl4 has been prepared and characterized by X-ray diffraction,  IR and UV-Visible spectroscopies. The complex crystallizes in the monoclinic space group P21/n with a minimal tetrahedral distortion of the ZnCl42- ion and with lattice parameters: a =12.054 (2) Å, b =7.129 (3) Å, c =23.480 (2) Å, β = 100.67 (2)°, V = 1983.03 (1) Å3 and Z = 4. The crystal structure was solved and refined to R = 0.080 and RW = 0.227 with 9611 independent reflections. It can be described by organic layers of p-anisidinium cations held together by C-H…O hydrogen bonds parallel to (010) plane, linked to the inorganic groups of ZnCl42- anions through N-H…Cl hydrogen bonds, electrostatic and Van Der Waals interactions, to form a three-dimensional network.

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Published

2014-04-04

How to Cite

Rahmouni, H., Sta, W. S., & Rzaigui, M. (2014). Preparation and Characterization of bis (4-methoxyanilinium) tetrachlorozincate. JOURNAL OF ADVANCES IN CHEMISTRY, 10(3), 2355–2362. https://doi.org/10.24297/jac.v10i3.2284

Issue

Vol. 10 No. 3 (2014)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.