Synthesis, Crystal Structure, and Characterization of the first Organic Cation Hexaoxoperiodate

Authors

  • I. Wacharine Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna
  • Wajda Sta Smirani labratory of chemical materials. Departement of chemistry. Faculy of sciences, Bizerte
  • M. Rzaigui Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna

DOI:

https://doi.org/10.24297/jac.v9i1.2301

Keywords:

First organic cation periodate, Crystal structure, IR Spectroscopy, Thermogravimetric analysis, 13C NMR.

Abstract

The title compound is an organic-inorganic hybrid material. The single crystal X-ray diffraction investigation reveals that the studied compound crystallizes in the monoclinic system, space group P21/c with the following lattice parameters:               𑎠= 7.551 (2) Ã…, ð‘ = 6.694 (3) Ã…, ð‘ = 14.783 (2) Ã…, β = 97.61 (2)° and ð‘ = 2. The crystal lattice is composed of a discrete (H4IO6)− anion surrounded by piperazinium cations and water molecules. Complex hydrogen bonding interactions between the different chemical spices form a three-dimensional network. Room temperature IR, 13C NMR spectroscopy, thermogravimetric analysis and optical absorption of the title compound were recorded and analyzed. 

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Author Biography

Wajda Sta Smirani, labratory of chemical materials. Departement of chemistry. Faculy of sciences, Bizerte

Departement of Chemistry

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Published

2013-01-01

How to Cite

Wacharine, I., Smirani, W. S., & Rzaigui, M. (2013). Synthesis, Crystal Structure, and Characterization of the first Organic Cation Hexaoxoperiodate. JOURNAL OF ADVANCES IN CHEMISTRY, 9(1), 1776–1782. https://doi.org/10.24297/jac.v9i1.2301

Issue

Vol. 9 No. 1 (2014)

Section

Articles

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Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.