Synthesis and characterization of a new Organic – Inorganic sulfate (C5H6N2O)2[Co(H2O)6]3(SO4)4.2H2O

Authors

  • M. Mathlouthi Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna
  • S. Benmansour Instituo de Ciencia Molecular (ICMol), Universidad de Valencia, C/Catedrático José Beltrán, 246980 Paterna
  • M. Rzaigui Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna
  • W. Smirani Sta Laboratoire de chimie des matériaux, Faculté des sciences de Bizerte, 7021, Zarzouna

DOI:

https://doi.org/10.24297/jac.v10i4.5505

Keywords:

Organic-inorganic hybrid, Crystal structure, IR Spectroscopy, Band-gap.

Abstract

crystals of a new hybrid compound, (C5H6N2O)2[Co(H2O)6]3(SO4)4.2H2O, were synthesized in aqueous solution and characterized. This compound crystallizes in the triclinic system with the space group P-1, the unit cell :a=6.632(3) Å, b=11.769(5) Å, c=14.210(6) Å, α=67.86(4)°, β=81.32(4)°, γ=85.18(4)° and V=1015.14(8) Å3 . Its crystal structure can be described as a packing of alternated inorganic and organic layers. The different components are connected by a three-dimensional network of O-H…O and N-H…O hydrogen bonds. 

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Published

2014-08-28

How to Cite

Mathlouthi, M., Benmansour, S., Rzaigui, M., & Sta, W. S. (2014). Synthesis and characterization of a new Organic – Inorganic sulfate (C5H6N2O)2[Co(H2O)6]3(SO4)4.2H2O. JOURNAL OF ADVANCES IN CHEMISTRY, 10(4), 2639–2647. https://doi.org/10.24297/jac.v10i4.5505

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