SbCl3-Catalyzed conversion of ketones and aldehydes into gem-dihydroperoxides (DHPs) with 30% H2O2

Authors

  • Davood Azarifar Buali-sina university
  • Boshra Mahmoudi Bu-Ali Sina University
  • Kaveh Khosravi Arak University

DOI:

https://doi.org/10.24297/jac.v11i5.4473

Keywords:

Gem-dihydroperoxide, antimony trichloride, SbCl3, catalyst, ketone, aldehyde, hydrogen peroxide

Abstract

A simple and efficient conversion of ketones and aldehydes into corresponding gem-dihydroperoxides (DHPs) has been developed by SbCl3-catalyzed oxidation with 30% H2O2 at room temperature. The reactions proceeded smoothly under mild conditions at room temperature. Simple experimental procedure, use of inexpensive and non-toxic catalyst, high yields and low reaction times are the main merits of the present method.

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Author Biographies

Davood Azarifar, Buali-sina university

Department of Chemistry, Professor in Organic and Organometallic chemistry

Boshra Mahmoudi, Bu-Ali Sina University

Department of Chemistry, MSc Student

Kaveh Khosravi, Arak University

Department of Chemistry, Professor of organic chemistry

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Published

2015-04-18

How to Cite

Azarifar, D., Mahmoudi, B., & Khosravi, K. (2015). SbCl3-Catalyzed conversion of ketones and aldehydes into gem-dihydroperoxides (DHPs) with 30% H2O2. JOURNAL OF ADVANCES IN CHEMISTRY, 11(5), 3547–3553. https://doi.org/10.24297/jac.v11i5.4473

Issue

Vol. 11 No. 5 (2015)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.