Regioselective and facile oxidative thiocyanation of anilines and indoles with trans-3,5?dihydroperoxy-3,5?dimethyl?1,2?dioxolane

Authors

  • Davood Azarifar Buali-sina university
  • Maryam Golbaghi Bu-Ali Sina University, Zip Code 65178, Hamedan
  • Mahtab Pirveisian Bu-Ali Sina University, Zip Code 65178, Hamedan
  • Zohreh Najminejad Bu-Ali Sina University, Zip Code 65178, Hamedan

DOI:

https://doi.org/10.24297/jac.v10i8.2247

Keywords:

Trans-3, DHPODMDO, sodium thiocyanate, thiocyanation, anilines, indoles.

Abstract

Oxidative potential of trans3,5dihydroperoxy3,5dimethyl1,2dioxolane (DHPODMDO) has been explored in the facile thiocyanation of anilines and indoles through the efficient and in situ generation of SCN+ ion from sodium thiocyanate. The reactions proceed with regioselectivity under mild conditions at room temperature to afford the respective thiocyanate derivatives in excellent yields and low reaction times.

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Author Biographies

Maryam Golbaghi, Bu-Ali Sina University, Zip Code 65178, Hamedan

Faculty of Chemistry

Mahtab Pirveisian, Bu-Ali Sina University, Zip Code 65178, Hamedan

Faculty of Chemistry

Zohreh Najminejad, Bu-Ali Sina University, Zip Code 65178, Hamedan

Faculty of Chemistry

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Published

2014-08-02

How to Cite

Azarifar, D., Golbaghi, M., Pirveisian, M., & Najminejad, Z. (2014). Regioselective and facile oxidative thiocyanation of anilines and indoles with trans-3,5?dihydroperoxy-3,5?dimethyl?1,2?dioxolane. JOURNAL OF ADVANCES IN CHEMISTRY, 10(8), 3088–3096. https://doi.org/10.24297/jac.v10i8.2247

Issue

Vol. 10 No. 8 (2014)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.