Synthesis, crystal structure, NMR characterization, Thermal analysis and Spectroscopic Characteristics of [2,3-(CH3)2C6H3NH3]6P6O18.2H2O

Authors

  • RAMZI FEZAI Chemistry Laboratory of Materials LR13ES08, Sciences Faculty of Bizerta, 7021 Jarzouna, Bizerta
  • LAMIA KHEDHIRI Chemistry Laboratory of Materials LR13ES08, Sciences Faculty of Bizerta, 7021 Jarzouna, Bizerta
  • MOHAMED RZAIGUI Chemistry Laboratory of Materials LR13ES08, Sciences Faculty of Bizerta, 7021 Jarzouna, Bizerta

DOI:

https://doi.org/10.24297/jac.v11i2.2217

Keywords:

Cyclohexaphosphate, X-ray diffraction, Crystal structure, NMR study, Thermal analysis and IR spectroscopy.

Abstract

Single crystals of [2,3-(CH3)2C6H3NH3]6P6O18.2H2O were synthesized in aqueous solution. This compound crystalizes in the P 141">  Triclinic unit cell with the parameters a = 9.97 Å, b = 16.06 Å, c =18.62 Å, α = 93.03°,  b  = 89.75 °, g = 93.85°, and Z = 2. Its crystal structure, determined by X-ray diffraction, consists of inorganic layers parallel to the ac plane. The organic molecules are disposed parallel to the plane bc on either side of each inorganic layer on which are anchored by hydrogen bonds via their ammonium groups (N-H…O). Configuration of the asymmetric unit is characterized by FT-IR spectroscopy and solid state NMR study of 31P.

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Author Biographies

RAMZI FEZAI, Chemistry Laboratory of Materials LR13ES08, Sciences Faculty of Bizerta, 7021 Jarzouna, Bizerta

Chemistry Department

LAMIA KHEDHIRI, Chemistry Laboratory of Materials LR13ES08, Sciences Faculty of Bizerta, 7021 Jarzouna, Bizerta

Chemistry Department

MOHAMED RZAIGUI, Chemistry Laboratory of Materials LR13ES08, Sciences Faculty of Bizerta, 7021 Jarzouna, Bizerta

Chemistry Department

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Published

2016-01-01

How to Cite

FEZAI, R., KHEDHIRI, L., & RZAIGUI, M. (2016). Synthesis, crystal structure, NMR characterization, Thermal analysis and Spectroscopic Characteristics of [2,3-(CH3)2C6H3NH3]6P6O18.2H2O. JOURNAL OF ADVANCES IN CHEMISTRY, 11(2), 3498–3512. https://doi.org/10.24297/jac.v11i2.2217

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