Structural Study of a new Compound Based on Acid 1,4-Cyclohexanedicarboxylic (1,4-CDC)

Authors

  • Manel Halouani Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax
  • M. Dammak Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax
  • N. Audebrand Laboratoire de Matériaux Inorganiques: Chimie Douce et Réactivité, UMR 6226 Sciences Chimiques de Rennes, Université Rennes 1
  • L. Ktari Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax

DOI:

https://doi.org/10.24297/jac.v6i1.969

Keywords:

Hydrothermal synthesis, X-ray diffraction, Crystal structure

Abstract

One nickel 1,4-cyclohexanedicarboxylate coordination polymers, Ni2 [(O10C6H4)(COO)2].2H2O  (I), was hydrothermally synthesized from an aqueous solution of Ni (NO3)2.6H2O, (1,4-CDC) (1,4-CDC = 1,4-cyclohexanedicarboxylic acid) and tetramethylammonium nitrate. Compound (I) crystallizes in the monoclinic system with the C2/m space group. The unit cell parameters are a = 20.1160 (16) Å, b = 9.9387 (10) Å, c = 6.3672 (6) Å, β = 97.007 (3) (°), V= 1263.5 (2) (Å3) and Dx= 1.751g/cm3. The refinement converged into R= 0.036 and RW = 0.092. The structure, determined by single crystal X-ray diffraction, consists of two nickel atoms Ni (1) and Ni (2). Lots of ways of which is surrounded by six oxygen atoms, a carboxyl group and two water molecules.

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Published

2010-04-10

How to Cite

Halouani, M., Dammak, M., Audebrand, N., & Ktari, L. (2010). Structural Study of a new Compound Based on Acid 1,4-Cyclohexanedicarboxylic (1,4-CDC). JOURNAL OF ADVANCES IN CHEMISTRY, 6(1), 891–896. https://doi.org/10.24297/jac.v6i1.969

Issue

Vol. 6 No. 1 (2013)

Section

Articles

License

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