Structural Study of the Compound [(C10O8H2)2 (C4N2H6)].2H2O Synthesized by Hydrothermal Condition

Authors

  • Manel Halouani Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax
  • M. Abdelhedi Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax
  • M. Dammak Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax
  • N. Audebrand Laboratoire de Matériaux Inorganiques: Chimie Douce et Réactivité, UMR 6226 Sciences Chimiques de Rennes, Université Rennes 1, France
  • L. Ktari Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax

DOI:

https://doi.org/10.24297/jac.v4i2.2691

Keywords:

Hydrothermal synthesis, X-ray diffraction, Crystal structure

Abstract

A new metal–organic compound [(C10O8H2)2(C4N2H6)].2H2O(I) was hydrothermally synthesized from an aqueous solution of Fe (NO3)3 9H2O, (btec) (btec= 1, 2, 4, 5-benzenetetracarboxylic acid) and piperazine. Compound I crystallizes in the triclinic system with the P1 space group. The unit cell parameters are a = 8.271 Å, b = 8.500 Å, c = 9.660 Å, α = 87.12°, β = 89.53°, γ = 70.91°, Z= 2, V= 640.96(6) Å3 and Dx= 1.602g/cm3. The refinement converged into R= 0.047 and RW = 0.059. The structure, determined by single crystal X-ray diffraction, consists of two carboxyl group, piperazine and two molecules of water.

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Published

2008-08-08

How to Cite

Halouani, M., Abdelhedi, M., Dammak, M., Audebrand, N., & Ktari, L. (2008). Structural Study of the Compound [(C10O8H2)2 (C4N2H6)].2H2O Synthesized by Hydrothermal Condition. JOURNAL OF ADVANCES IN CHEMISTRY, 4(2), 377–386. https://doi.org/10.24297/jac.v4i2.2691

Issue

Vol. 4 No. 2 (2013)

Section

Articles

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