Inhibitive Effect of Urea and Urea Derivatives on the Corrosion of Silver in Acetic Acid Solutions
DOI:
https://doi.org/10.24297/jac.v6i2.5543Keywords:
Silver, Acetic acid, Corrosion inhibition, Potentiodynamic polarization and Temkin isothermAbstract
The corrosion of silver in acetic acid was studied using potentiodynamic polarization technique in absence and presence of different concentrations of urea, thiourea and N-allylthiourea. The inhibition efficiency was found to depend on both the inhibitor type and concentration. The inhibitive action of these compounds is based on the formation of salt complex and/or the adsorption of the protonated species on the metal surface according to Temkin's isotherm. The thermodynamic parameters Kads and ΔG°adsfor the adsorption process are calculated and discussed.
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