Inhibitive Effect of Urea and Urea Derivatives on the Corrosion of Silver in Acetic Acid Solutions

Authors

  • S. Abd El Wanees Chemistry Department, Faculty of Science, Tabuk University, Tabuk, Kingdom of Saudi Arabia Chemistry Department, Faculty of Science, Zagazig University, Zagazig 44519, Egypt
  • A.M.A Shehata Faculty of Education 45111, Suez Canal University, Al-Arish
  • M. Barakat Tabuk University, Tabuk
  • A. Hathoot Menoufia University, Menoufia

DOI:

https://doi.org/10.24297/jac.v6i2.5543

Keywords:

Silver, Acetic acid, Corrosion inhibition, Potentiodynamic polarization and Temkin isotherm

Abstract

The corrosion of silver in acetic acid was studied using potentiodynamic polarization technique in absence and presence of different concentrations of urea, thiourea and N-allylthiourea. The inhibition efficiency was found to depend on both the inhibitor type and concentration. The inhibitive action of these compounds is based on the formation of salt complex and/or the adsorption of the protonated species on the metal surface according to Temkin's isotherm. The thermodynamic parameters Kads and ΔG°adsfor the adsorption process are calculated and discussed.

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Author Biographies

A.M.A Shehata, Faculty of Education 45111, Suez Canal University, Al-Arish

Chemistry Department

M. Barakat, Tabuk University, Tabuk

Chemistry Department, Faculty of Science

A. Hathoot, Menoufia University, Menoufia

Department of Chemistry, Faculty of Science

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Published

2014-01-10

How to Cite

Wanees, S. A. E., Shehata, A., Barakat, M., & Hathoot, A. (2014). Inhibitive Effect of Urea and Urea Derivatives on the Corrosion of Silver in Acetic Acid Solutions. JOURNAL OF ADVANCES IN CHEMISTRY, 6(2), 1038–1048. https://doi.org/10.24297/jac.v6i2.5543

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