Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole

Authors

  • Araceli Vega-Paz Instituto Mexicano del Petróleo (IMP) Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacan, México D.F., 07730
  • Luisa E. Montiel Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F
  • Carolina Zuriaga-Monroy Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.
  • José-Manuel Martínez-Magadán Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.
  • Jesús Marín-Cruz Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F

DOI:

https://doi.org/10.24297/jac.v7i3.2387

Keywords:

N-(α-amino-alkyl)-benzotriazole, DSC, TGA, Density Functional Theory, thermal stability

Abstract

N-(α-amino-alkyl)-benzotriazole, a derivative of Benzotriazole (BTZ), was synthesized via a Mannich reaction addition. The chemical characterization shows that when C19H32N4supramolecule is subjected to heating process the covalent bonds of aminal carbon are broken, modifying supramolecule structure, this results in a rearrangement to the structure dodecan ammonium-1-benzotriazol-1-ate, [BTZ- amine12+].Quantum chemical calculations based on DFT method were performed on the C19H32N4 molecule. The results show that in a derivative of BTZ exists a weak bond where its break may occur.

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Author Biographies

  • Araceli Vega-Paz, Instituto Mexicano del Petróleo (IMP) Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacan, México D.F., 07730
    Programa de Ingeniería Molecular
  • Luisa E. Montiel, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F
    Programa de Ingeniería Molecular
  • Carolina Zuriaga-Monroy, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.
    Programa de Estudios de Posgrado
  • José-Manuel Martínez-Magadán, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.

    Programa de Recuperación de Hidrocarburos

  • Jesús Marín-Cruz, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F

    Programa de Ingeniería Molecular

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Published

2011-12-17

Issue

Vol. 7 No. 3 (2014)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole. (2011). JOURNAL OF ADVANCES IN CHEMISTRY, 7(3), 1440-1447. https://doi.org/10.24297/jac.v7i3.2387

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