Bis(3-phenylpropylammonium) dichromate (VI): Synthesis, crystal structure and spectroscopy studies

Authors

  • Sonia Trabelsi 7021 Zarzouna Bizerte, Université de Carthage
  • Thierry Roisnel Centre de Diffractométrie X, UMR6226 CNRS, Unité Sciences Chimiques de Rennes, Université de Rennes I, 263 Avenue du General Leclerc, 35042 Rennes
  • Houda Marouani 7021 Zarzouna Bizerte, Université de Carthage

DOI:

https://doi.org/10.24297/jac.v11i1.2227

Keywords:

Organic-inorganic hybrid material, dichromate (VI), Single crystal X-ray, IR Spectroscopy, UV-visible Spectroscopy.

Abstract

The structure of bis(3-Phenylpropylammonium) dichromate(VI) was determined from X-ray diffraction data. The compound crystallizes in the monoclinic system (space group P21/c) with the lattice parameters: a = 7.9379(2) Å, b = 36.2439(16) Å, c = 7.5753(3) Å; B = 96.069(2); V= 2167.20(14) Å3 and Z = 4. The structure was solved from 4959 independent reflections with R = 0.043 and Rw = 0.105. The structure consists of discrete dichromate anions (Cr2O72-) with eclipsed conformation stacked in layers parallel to (a, c) plane at y = 0 and ½. These anions are linked via the 3-phenylpropylammonium cations by N—H…O and C—H…O hydrogen bonds, forming a two-dimensional supramolecular network. Crystal structure and spectroscopic studies are reported for the bis(3-phenylpropylammonium) dichromate(VI).

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Author Biographies

Sonia Trabelsi, 7021 Zarzouna Bizerte, Université de Carthage

Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte

Houda Marouani, 7021 Zarzouna Bizerte, Université de Carthage

Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte

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Published

2016-12-17

How to Cite

Trabelsi, S., Roisnel, T., & Marouani, H. (2016). Bis(3-phenylpropylammonium) dichromate (VI): Synthesis, crystal structure and spectroscopy studies. JOURNAL OF ADVANCES IN CHEMISTRY, 11(1), 3394–3403. https://doi.org/10.24297/jac.v11i1.2227

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