Synthesis and thermodynamics of the reactions of [Pd(Eten)(H2O)2]2+ with ligands of biological significane with reference to the antitumour activity

Authors

  • Fawzia Al-Kallaf Cairo University, P.O. Box 12611
  • Perihan A. Khalf-Allaa Cairo University, P.O. Box 12611
  • Abeer Al-Bassam Cairo University, P.O. Box 12611
  • Mohamed M. Shoukry Cairo University, P.O. Box 12611

DOI:

https://doi.org/10.24297/jac.v11i1.2222

Keywords:

palladium diamine complexes / bioligands / equilibrium constants.

Abstract

Pd(Eten)Cl2  complex, where Eten = N-ethylethylenediamine , was synthesized and characterized by elemental analysis and spectroscopic techniques. The stoichiometry and stability of the complexes formed between [Pd(Eten)(H2O)2]2+ and various biologically relevant ligands  as adenine, adenosine, adenosine-5’-monophosphate  and some selected peptides  were investigated at 25ºC and 0.1 M ionic strength. The speciation diagrams of the complexes formed in solutions are evaluated. Thermodynamic parameters for Pd(Eten)-glycylglycine complexes were estimated.

Downloads

Download data is not yet available.

Author Biographies

  • Fawzia Al-Kallaf, Cairo University, P.O. Box 12611
    Department of Chemistry, Faculty of Science
  • Perihan A. Khalf-Allaa, Cairo University, P.O. Box 12611
    Department of Chemistry, Faculty of Science
  • Abeer Al-Bassam, Cairo University, P.O. Box 12611
    Department of Chemistry, Faculty of Science
  • Mohamed M. Shoukry, Cairo University, P.O. Box 12611
    Department of Chemistry, Faculty of Science

Downloads

Published

2016-12-17

Issue

Vol. 11 No. 1 (2015)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

Synthesis and thermodynamics of the reactions of [Pd(Eten)(H2O)2]2+ with ligands of biological significane with reference to the antitumour activity. (2016). JOURNAL OF ADVANCES IN CHEMISTRY, 11(1), 3324-3334. https://doi.org/10.24297/jac.v11i1.2222

Similar Articles

1-10 of 30

You may also start an advanced similarity search for this article.