A Novel Synthesis of (Z)-ethyl 3-amino-2-cyano-3-phenyl(or alkyl)acrylate and ethyl- 2-cyano-3-phenyl-3-propionylimino-propanoate

Authors

  • Fathi Zribi Laboratoire de Chimie Appliquée : Hétérocycles, Corps gras et Polymères à la Faculté des Sciences de Sfax. Route de Soukra Km 3.5. BP 802. Sfax 3000
  • Mohamed Belhouchet Laboratoire Physico-Chimie de l’Etat Solide, Faculté des Sciences de Sfax. Route de Soukra Km 3.5. BP 802. Sfax 3000
  • Fakher Chabchoub Laboratoire de Chimie Appliquée : Hétérocycles, Corps gras et Polymères à la Faculté des Sciences de Sfax. Route de Soukra Km 3.5. BP 802. Sfax 3000

DOI:

https://doi.org/10.24297/jac.v9i3.1012

Keywords:

Imidate, N-acetyl imidate, N-ethoxycarbonyl imidate, ethyl cyanoacetate, X-ray diffraction, H-bonds.

Abstract

Reaction between ethyl cyanoacetate and imidate, N-acetyl imidate and N-ethoxycarbonyl imidate in basic medium are student. The structure and geometrically configuration of (Z)-ethyl 3-amino-2-cyano-4-phenylbut-2-enoate 3c was established by X-ray diffraction. The functionality in ethyl 2-cyano-3-(ethoxycarbonyl)-3-p-tolylacrylate 7b was exploited to get the desired heterocycle.  

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Published

2013-12-01

How to Cite

Zribi, F., Belhouchet, M., & Chabchoub, F. (2013). A Novel Synthesis of (Z)-ethyl 3-amino-2-cyano-3-phenyl(or alkyl)acrylate and ethyl- 2-cyano-3-phenyl-3-propionylimino-propanoate. JOURNAL OF ADVANCES IN CHEMISTRY, 9(3), 2056–2061. https://doi.org/10.24297/jac.v9i3.1012

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Articles