Synthesis, structure and characterization of a new cadmium(II) iodide containing a tetradentate tripodal amine

Authors

  • Kamel Kaabi Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna
  • Valeria Ferretti Department of Chemical and Pharmaceutical Sciences and Center for Structural Diffractometry, via Fossato di Mortara 17, I-44121 Ferrara
  • Frederic Lefebvre Laboratoire de Chimie Organometallique de Surface (LCOMS), Ecole Supérieure de Chimie Physique Electronique, 69622 Villeurbanne Cedex
  • Cherif Ben Nasr Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna

DOI:

https://doi.org/10.24297/jac.v10i5.890

Keywords:

Cadmium(II) iodide compound, Tripodal amine, X-ray structure, CP-MAS NMR, DTF calculations

Abstract

A cadmium(II) iodide compound of the [Cd(L)I]I series, with L = tris(2-aminoethyl)amine, is synthesized and characterized. X-ray structural study shows that the title compound has a slightly distorted trigonal bipyramidal environment where the CdN4I chromophore is bounded by N atoms of L and one iodide. In the structural arrangement, the [Cd(L)I]+ cationic complexes are interconnected via N-H···I hydrogen bonds generated by the uncoordinated I iodide anions to form layers parallel to the (a, c) plane. The 13C CP-MAS NMR spectrum is discussed and the vibrational absorption bands were identified by infrared spectroscopy and DFT calculations.

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Published

2014-06-03

How to Cite

Kaabi, K., Ferretti, V., Lefebvre, F., & Ben Nasr, C. (2014). Synthesis, structure and characterization of a new cadmium(II) iodide containing a tetradentate tripodal amine. JOURNAL OF ADVANCES IN CHEMISTRY, 10(5), 2728–2736. https://doi.org/10.24297/jac.v10i5.890

Issue

Vol. 10 No. 5 (2014)

Section

Articles

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Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.