The Periodic Table needs negative orbitals in order to eliminate quantum weirdness: a new quantum chemistry mathematics

A new quantum chemistry mathematics

Authors

DOI:

https://doi.org/10.24297/jac.v17i.8865

Keywords:

quantum weirdness, zero energy waves, hydrogen orbitals, Theory of Elementary Waves (TEW)

Abstract

A consensus among quantum experts is that the quantum world is not properly understood. It is a mistake to think we can cure quantum weirdness by tinkering with superficial aspects of quantum mechanics (QM). We propose that nature uses  (–ψ) as its wave function, whereas QM uses (+ψ). We propose therefore that the Periodical Table should be changed to negative orbitals (–ψ). Surprisingly, this change makes almost no difference to chemistry on a practical level. The Born rule takes the absolute square of an amplitude to obtain a probability to test in chemistry lab P=|–ψ|2=|+ψ|2. We propose a new math based on (–ψ) that is the mirror image of quantum mathematics. We call it the Theory of Elementary Waves (TEW). The negative sign is not an electrical charge. It has nothing to do with Coulomb’s law. Valence electrons are unchanged. Ions, covalent bonds, dipoles, metals, hydrogen bonding and the hydrogen 21 cm line are unchanged. The octet rule and rules for drawing dot structures of molecules do not change. Amino acids, sugars and DNA do not change their handedness. We cite abundant experimental evidence showing that TEW is correct and QM is wrong.

Downloads

Download data is not yet available.

References

J. Baggott, The Quantum Story: a history in 40 moments, Oxford University Press, 2011. ISBN:978–0-19-956684-6

M. Barone, “Obituary: Franco Selleri (1936 - 2013),” CERN Courier, (Feb 24, 2014) http://cerncourier.com/cws/article/cern/56228. (access date: Feb 9, 2015. No longer available.)

A. Becker, What Is Real? Basic Books, 2018. ISBN:978–0-19-956684-6

M. Born, “Zur Quantenmechanik der Stoßvorgänge [On the quantum mechanics of collisions]. Zeitschrift für Physik, 37,” pp. 863-867, 1926. In J. A. Wheeler and W. H. Zurek (eds.), Quantum Theory and Measurement, Princeton, pp. 50-55, 1983. ISBN 978-0-691-08316-2. DOI: 10.1007/BF01397477

J. H. Boyd, “There are two solutions to the equations of Feynman’s Quantum Electrodynamics (QED); the newly discovered solution is free of quantum weirdness,” Journal of Advances in Physics, vol. 18, pp. 39-57, 2020. DOI: 10.24297/jap.v18i.8831.

J. H. Boyd, “If the propagator of QED were reversed, the mathematics of Nature would be much simpler,” Journal of Advances in Mathematics, vol. 18, pp. 129-153, 2020. DOI: 10.24297/jam.v18i.8746

J. H. Boyd, “A tiny, counterintuitive change to the mathematics of the Schrödinger wave packet and Quantum ElectroDynamics could vastly simplify how we view Nature,” Journal of Advances in Physics, vol. 17, pp. 169-203, 2020. DOI: 10.24297/jap.v17i.8696

J. H. Boyd, “New Schrödinger wave mathematics changes experiments from saying there is, to denying there is quantum weirdness,” Journal of Advances in Mathematics, vol. 18, pp. 82-117, 2020. DOI: 10.24297/jap.v17i.8696

J. H. Boyd, “Decrypting the central mystery of quantum mathematics: Part 1. The double slit experiment,” Journal of Advances in Mathematics, 2 vol. 17, pp. 255-282, 2019. DOI: 10.24297/jam.v17i0.8475

J. H. Boyd, “Decrypting the Central Mystery of Quantum Mathematics: Part 2. A mountain of empirical data supports TEW,” Journal of Advances in Mathematics, vol. 17, pp. 283-314, 2019. DOI: 10.24297/jam.v17i0.8489

J. H. Boyd, “Decrypting the central mystery of quantum mathematics: Part 3. A non-Einstein, non-QM view of Bell test experiments,” Journal of Advances in Mathematics, vol. 17, pp. 315-331, 2019. DOI: 10.24297/jam.v17i0.8490

J. H. Boyd, “Decrypting the central mystery of quantum mathematics: Part 4. In what medium do Elementary Waves travel?” Journal of Advances in Mathematics, vol. 17, pp. 332-351, 2019. DOI: 10.24297/jam.v17i0.8491

J. H. Boyd, “The quantum world is astonishingly similar to our world,” Journal of Advances in Physics, vol. 14, pp. 5598-5610, 2018. DOI: 10.24297/jap.v14i2.7555

J. H. Boyd, “The von Neumann and double slit paradoxes lead to a new Schrödinger wave mathematics,” Journal of Advances in Physics, vol.14, pp. 5812-5834, 2018. doi.org/10.24297/jap.v14i3.7820

J. H. Boyd, “The Boyd Conjecture,” Journal of Advances in Physics, vol. 13, pp. 4830-4837, 2017. DOI: 10.24297/jap.v13i4.6038

J. H. Boyd, “A symmetry hidden at the center of quantum mathematics causes a disconnect between quantum math and quantum mechanics,” Journal of Advances in Mathematics, vol. 13, pp. 7379-7386, 2017. DOI: 10.24297/jam.v13i4.6413

J. H. Boyd, “Paul Dirac’s view of the Theory of Elementary Waves,” Journal of Advances in Physics, vol. 13, pp. 4731-4734, 2017. DOI: 10.24297/jap.v13i3.5921

J. H. Boyd, “A paradigm shift in mathematical physics, Part 1: The Theory of Elementary Waves (TEW),” Journal of Advances in Mathematics, vol. 10, pp. 3828-3839, 2015. DOI: 10.24297/jam.v10i9.1908

J. H. Boyd, “A paradigm shift in mathematical physics, Part 2: A new local realism explains Bell test & other experiments,” Journal of Advances in Mathematics, vol. 10, pp. 3828-3839, 2015. DOI: 10.24297/jam.v10i9.1884

J. H. Boyd, “A paradigm shift in mathematical physics, Part 3: A mirror image of Feynman’s quantum electrodynamics (QED),” Journal of Advances in Mathematics, vol. 11, pp. 3977-3991, 2015. DOI: 10.24297/jam.v11i2.1283

J. H. Boyd, “A paradigm shift in mathematical physics, Part 4: Quantum computers and the local realism of all 4 Bell states,” Journal of Advances in Mathematics, vol. 11, pp. 5476-5493, 2015. DOI: 10.24297/jam.v11i7.1224

J. H. Boyd, “The Theory of Elementary Waves eliminates Wave Particle Duality,” Journal of Advances in Physics, vol. 7, pp. 1916-1922, 2015. DOI: 10.24297/jap.v7i3.1576

J. H. Boyd, “A new variety of local realism explains a Bell test experiment,” Journal of Advances in Physics, vol. 8, pp. 2051-2058, 2015. DOI: 10.24297/jap.v8i1.1541

J. H. Boyd, “A proposed physical analog of a quantum amplitude,” Journal of Advances in Physics, vol. 10, pp. 2774-2783, 2015. DOI: 10.24297/jap.v10i3.1324

J. H. Boyd, “Re-thinking a delayed choice quantum eraser experiment: a simple baseball model,” Physics Essays, vol. 26, pp. 100-109, 2013. DOI: 10.4006/0836-1398-26.1.100

J. H. Boyd, “Re-thinking Alain Aspect’s 1982 Bell test experiment with delayed choice,” Physics Essays, vol. 26, pp. 582-591, 2013. DOI: 10.4006/0836-1398-26.1.100 10.4006/0836-1398-26.4.582

J. H. Boyd, “Rethinking a Wheeler delayed choice gedanken experiment,” Physics Essays, vol. 25, pp. 390-396, 2012. DOI: 10.4006/0836-1398-25.3.390

Davisson, C. J. and L. Germer, “Reflection of electrons by a crystal of nickel.” Nature, 119 558-560 (1927). DOI: 10.1038/119558a0

Davisson, C.J., “The diffraction of electrons by a crystal of nickel,” Bell System Technical Journal, 7 90-105 (1928a). DOI: 10.1002/j.1538-7305.1928.tb00342.x

Davisson, C. J. “Are Electrons Waves?” Franklin Institute Journal, 205, 597 (1928b). DOI: 10.1016/S0016- 0032(28)90979-5

Eagle, B. “Schrödinger equation – a simple derivation,” (2012). https://www.youtube.com/watch?v=IsX5iUKNT2k&t=5s

R. P. Feynman, QED: The Strange Theory of Light and Matter, Princeton University Press, 1985. ISBN 978-0-691- 12575-6

R. P. Feynman, Feynman Lectures on Physics, vol. 2. New York: Basic Books, c1964. ISBN-13: 978-0-4650294-0

R. P. Feynman and A. R. Hibbs, Quantum Mechanics and Path Integrals, Mineola, NY: Dover Publications, c1965. ISBN-13 978-0-468-47722-0.

O. Freire. “Interview with Dr. Franco Selleri,” American Institute of Physics: Oral History Interviews (2003). https://www.aip.org/history-programs/niels-bohr-library/oral-histories/28003-1. and https://www.aip.org/history- programs/niels-bohr-library/oral-histories/28003-2. (accessed Sept 2, 2020)

H. Haber, “The spherical harmonics,” Physics II6C: Mathematical methods in physics III, University of California, Santa Cruz, http://scipp.ucsc.edu/~haber/ph116C/SphericalHarmonics_12.pdf (access date 9/17/2020).

H. Kaiser, R. Clothier, S. Werner, et. al., "Coherence and spectral filtering in neutron interferometry," Physical Review A, vol. 45, pp. 31-42, 1992. DOI: 10.1103/PhysRevA.45.31

Y.H., Kim, R. Yu, S.P. Kulik, Y.H. Shih, M. O. Scully, "A delayed choice quantum eraser," Physical Review Letters 8: 1–5, (2000). DOI: 10.1103/PhysRevLett.84.1

T. S. Kuhn, The Structure of Scientific Revolutions, (Chicago: U. of Chicago Press, 1970. ISBN 978-0-226-45803-8.

Libretexts project, “The Schrödinger Wave Equation for the Hydrogen Atom,” University of California Davis, 2016. https://chem.libretexts.org/Courses/University_of_California_Davis/UCD_Chem_107B%3A_Physical_Chemistry_for_Life_Scientists/Chapters/4%3A_Quantum_Theory/4.10%3A_The_Schrödinger_Wave_Equation_for_the_Hydrogen_Atom (access date 08/22/2020).

L. E. Little, “Theory of Elementary Waves,” Physics Essays, vol. 9, pp. 100-134, 1996. DOI: 10.4006/1.3029212

L. E. Little, “Theory of Elementary Waves @ JPL, Feb 2000,” https://www.youtube.com/watch?v=3_9LB0RzgWg

L. E. Little “Introduction to Elementary Waves,” 2016. https://www.youtube.com/watch?v=xx5V03iCbAo&t=16s

L. E. Little, “We have seen these waves,” 2016. https://www.youtube.com/watch?v=xWMiNsD_xdM&t=5s

R. L. Pfleegor and Leonard Mandel, “Interference of independent photon beams,” Physical Review, 159, 1084-1088, 1967. DOI: 10.1103/PhysRev.159.1084

R. L. Pfleegor and Leonard Mandel. Further experiments on interference of independent photon beams at low light levels. Journal of the Optical Society of America, 58, 946-950, 1968. DOI: 10.1364/JOSA.58.000946

A. Wegener, The Origin of Continents and Oceans, translated by John Biram, New York, Dover Publications Inc.1966, Library of Congress Catalog Card Number: 66-28270.

Downloads

Published

2020-10-11

How to Cite

Jeffrey H. Boyd. (2020). The Periodic Table needs negative orbitals in order to eliminate quantum weirdness: a new quantum chemistry mathematics : A new quantum chemistry mathematics . JOURNAL OF ADVANCES IN CHEMISTRY, 17, 88–125. https://doi.org/10.24297/jac.v17i.8865

Issue

Section

Articles