Ionic behavior, Na+ mobility and infrared spectroscopy in Na7Cr4(P2O7)4PO4 material
DOI:
https://doi.org/10.24297/jac.v10i7.6811Keywords:
Three-dimensional structures, Tunnels, Rietveld, IR spectroscopy, Ionic Conductor, BVSAbstract
The title compound, heptasodium tetrachromium(III) tetrakis(diphosphate) orthophosphate, was synthesized by solid state reaction. Its structure is isotypic with that of Na7M4(P2O7)4PO4 (M = In, Al) compounds and is made up from a three-dimensional [(CrP2O7)4PO4]7- framework with channels running along [001]. The Na+ cations are located in the voids of the framework. This compound has been investigated by X-ray diffraction and infrared (IR) spectroscopy. The conductivity measurements of the compound were carried out from 515 to 795 Kelvin using the frequency response analyzer with 0.05V amplitude signal over the range of 13MHz-5Hz. The conductivity of the sample at 574K is 0.45 10-6 S.cm-1. The activation energy Ea=0.73eV shows that Na7Cr4(P2O7)4PO4 is a medium ionic conductors. The monovalent cations conduction pathways in the crystal bulks are simulated by means of the bond valence model (BVS).
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References
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[3] J. Alamo & R. Roy. J. Am. Ceram. Soc., 67 (1984) 78–80.
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[8] O. Shigeto, S. Shoichiro, E. Minato, Y. Jun-ichi, J. Power Sources, 97–98 (2001) 430 – 432.
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[12] L. Vijayan, R. Cheruku, G. Govindaraj, S. Rajagopan, Mater. Chem. Phys., 130 (3) (2011) 862–869.
[13] Yu. Pinus, A. V. Khoroshilov, K. S. Gavrichev, V. P. Tarasov, A. B. Yaroslavtsev, Solid State Ionics, 212 (2012) 112-116.
[14] C. Chen, G.B. Liu, Y. Wang, J.L. Li, H. Liu, Electrochim. Acta, 113 (2013) 464–469.
[15] E. Markevich, R. Sharabi, O. Haik, V. Borgel, G. Salitra, D. Aurbach, G. Semrau, M.A. Schmidt, N. Schall, C. Stinner, J. Power Sources, 196 (15) (2011) 6433–6439.
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[20] N. V. Stus, V. V. Lisnyak, & P. G. Nagornyi, J. Alloys Compd., 314 (2001) 62–66.
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[22] N. Bourguiba Fakhar, M. F. Zid and A. Driss, Acta Cryst., E69 (2013) i27–i28.
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[32] Bruker-AXS (2008). Diffracplus Evaluation package EVA 14, Release 15 (Computer Software) Bruker AXS GmbH Karlsruhe, Germany.
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[35] Johnson, D. 1990—2007, Zview version 3.1c, Scibner Associates, Inc.
[36] M. Marzouki, A. Guesmi, M.F. Zid, A. Driss, Crystal Structure Theory and Applications, 1 (2012) 68–73.
[37] F. Sanz, C. Parada, J.M. Rojo and C. RuÃz-Valero, Chem. Mater., 13 (4) (2001) 1334–1340.
[38] J. M. Wimand, P. Tarte, C. R. Acad. Sci. Paris, Series II, 307 (1988) 1857–1862.
[39] N. Fakhar Bourguiba, N. Gharbi, L. Smiri Dogguy, J.P. Boilot, Mat. Res. Bull., 23 (1988) 1185–1191.
[40] I. D. Brown, ―The Chemical Bond in Inorganic Chemistry - The Bond Valence Model,‖ IUCr Monographs on Crystallography, 12, Oxford University Press, 2002.
[41] S. Adams, ―Softbv‖, 2003. http://kristall.uni.mki.gwdg.de/softbv
[42] D. Mazza, S. Ronchetti, O. Bohnké, H. Duroy, J. L. Fourquet, Solid State Ionics, 149 (1-2) ( 2002) 81–88.
[43] D. Mazza, J. Solid State Chem., 156 (1) (2001) 154–160.
[44] G. Corbel, D. Mazza, O. Bohnké, M. Leblanc, Solid State Sciences, 7 (2005) 588–593.
[45] R. Ben Amor, A. Guesmi, D. Mazza, M. F. Zid, Journal de la Société Chimique de Tunisie, 10 (2008) 83–92.
[46] D. Mazza, J. Solid State Chem., 156 (2001) 154–160.
[47] B. Bouzemi, H. Boughzala and T. Jouini, J. Solid State Chem., 173, 273 (2003).
[48] S. Kouass and H. Boughzala, Phosphorus, Sulfur Silicon Relat. Elem., 181 (2006) 2641–2652.
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Published
2014-10-30
How to Cite
Bourguiba, N. F., Boughazala, H., & Zid, M. F. (2014). Ionic behavior, Na+ mobility and infrared spectroscopy in Na7Cr4(P2O7)4PO4 material. JOURNAL OF ADVANCES IN CHEMISTRY, 10(7), 2955–2966. https://doi.org/10.24297/jac.v10i7.6811
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