Effect the Temperature on Structure and Optical Properties for ZnS nanostructure Thin Film
DOI:
https://doi.org/10.24297/jac.v11i2.6689Keywords:
Nanocrystalline, ZnS, CBD method, optical propertiesAbstract
ZnS nanocrystalline thin films by different temperature of reaction were prepared by chemical bath deposition using thiourea and zinc acetate as S2– and Zn2+ source. The optical absorption studies in the wavelength range 200–1100 nm show that band gap energy of samples 3.75 and 4.0 eV for different temperature reaction condition. The refractive index was estimated within the visible wavelength at 623 nm, it was 2.04 for sample 1 and its value will increase for sample 2 to be 2.55. The room temperature photoluminescence spectra of the films showed two peaks for all samples. We assigned the first peak due to band gap transitions while the latter was due to zinc vacancy in the films. Structural analysis using atomic force microscopy shows that the grain size for films were 73.2 and 87.34 nm. X-ray diffraction analysis indicates that both of them formed in the reaction bath have cubic zinc blende structure .The structural estimation shows variation in grain size 7nm and 20nm with different temperature reaction.
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References
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[2] Yang, Q., Wang, K., C., Zhang, D., Qian , Y., "The synthesis of SnS2 nanoflakes from tetrabutyltin precursor", J. Sol. State Chem., 164 (2002) 106–109.
[3] Wang, Y., Ma, C., Sun, X. H., Li, "Preparation of nanocrystalline metal oxide powders with the surfactant - mediated method", Inorg. Chem. Comm., 5 (2002) 751–755.
[4] Benavente, E. M., Santa Ana A, Mendizabal , F., Gonzalez G, "Intercalation chemistry of molybdenum disulfide", Coord. Chem. Rev., 224 (2002) 87–109.
[5] Borah, J.P., Barman, J. and Sarma ,K.C., "Structural and optical properties of ZnS nanoparticales", Chalcogenide Letters, 5 (2008) 201- 208.
[6] Li-li ,W., Jin-bo, Z. Ke, Yuan-chang, Z., S. and You-shi , W. , " Controllable morphologies of ZnO nanocrystals and the photoluminescence property' , Journal of Synthetic Crystals, 38(2009) 689−692.
[7] Wen-de, C. and Ping, W., " Synthesis and strong blue light emission properties of ZnO tetrapod nanostructure", Chinese Journal of Luminescence, 27(2006) 608−613.
[8] Hong-yan, X. , Xiu-lin, L. , . De-liang ,C, . Mei, L, Qi-long, W. and Min-hua, J., "Study on thick film gas sensors fabricated by using ZnO nanopowder", Journal of Functional Materials and Devices, 11(2005) 241−245.
[9] Dimos, K., Koutselas, I. B. and Karakassides , M.A, "Synthesis and characterization of ZnS nanosized semiconductor particles within mesoporous solids", The Journal of Physical Chemistry B, 110(2006) 22339−22345.
[10] Dhas N. A, Zaban , A. and Gedanken ,A. 1999. "Surface synthesis of zinc sulfide nanoparticles on silica microspheres: sonochemical preparation, characterization, and optical properties", Chemistry of Materials, 11(1999) 806−813.
[11] Wang, L. P. and Hong, G. Y. 2000. " A new preparation of zinc sulfide nanoparticles by solid-state method at low temperature", Materials Research Bulletin, 35(2000): 695−701.
[12] Zhao, Z. G., Geng ,F. X., Cong, H. T., Bai ,J .B. and Cheng , H. M. 2005 ."A simple solution route to controlled synthesis of ZnS submicrospheres, nanosheets and nanorods", Nanotechnology, 17(2006) 4731−4735.
[13] Chai , L. L., Zhu, Y. C., Du , J. , Zou,G. F. and Qian , Y.T. 2005. " One-step hydrothermal method to synthesize self-encapsulated ZnS micron core-shell spheres on a large scale", Chemistry Letters, 34 (2005) 1324−1325.
[14] Kolba ,D. M., Ullmanna ,R. and Zieglera,J.C.1998, " Electrochemical nanostructuring , Electrochimica Acta", 43(1998) 2751−2760.
[15] Ubale.. A. U., Sangawar V. S and Kulkarni, D. K. 2007. " Size dependent optical characteristics of chemically deposited nanostructured ZnS thin films, Bull. Mater. Sci., 30, ( 2007) 147–151.
[16] Shinde M. S., Ahirrao P. B., Patil , R. S. 2001 "Structural, Optical and Electrical Properties of Nanocrystalline ZnS thin films Deposited by Novel Chemical Route, Archives of Applied Science Research, 3 ( 2011) 311-317.
[17] Nabiyouni, G., Sahraei, R. , Toghiany, M., Majles M. H. and Hedayati, K. 2011. "Preparation and characterization of nanostructured ZnS thin films grown on glass and n-type Si substrates using anew chemical bath deposition technique" , Rev.Adv.Mater.Sci. 27(2011) 52-57.
[18] Longhurst , R.S. 1957. Geometrical and Physical Optics, Longmans Green, London.
[19] cottrell, A. 1975. Intorduction to Mettallurgy ,Arnold, Londan, P.173
[20] Bo, J., rah, .P. and Sarma, K.C. 2008." Optical and Optoelectronic Properties of ZnS Nanostructured Thin Film", ACTA PHYSICA POLONICA A, 114 (2008) 713-719.
[21] Tiwari, A., Khan , S .A. and Kher, R. S. 2011. "Advances in Applied Science Research" , 2 (2011) 105-110.
[22] Moss, T.S. 1986. “Infrared Physics†26, 5, (1986) 335-336.
[23] Liu, X. , Cai, X., Mao, J., and Jin,C. 2001. "ZnS/Ag/ZnS nano-multilayer films for transparent electrodes",. Appl. Surf.
Sci. ,183(2001) 103-110.
[24] Hariskos, D., Spiering, S., and Powalla, M.2005. "Buffer layer in Cu(In)Se solar cell and mo dules", Thin Solid Films.
480,( 2005) 99-109.
[25] Ãœzar, N. and Arikan, M. 2011. "Synthesis and investigation of optical properties of ZnS nanostructures", Bull. Mater.
Sci., 34, (2011), 287–292.
[26] John ,R., Florence, S. 2010. " Optical, structural and morphological studies of beanlike ZnS nanostructures by
aqueous chemical method", Chalcogenide Letters , 7(2010). 269 – 273.
[27] Kurbatov, D., Оpan ,A., Kshnyakina ,S., Мelnik, V.and Nesprava, V. 2010. " Luminescent and optical characteristics
of zinc sulfide thin filoms produced by close-spaced vacuum sublimation" , Rom. Journ. Phys., 55(2010) 213–219.
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Published
2015-01-17
How to Cite
Abbas, N. K., Al- Rasoul, K. T., & Shanan, Z. J. (2015). Effect the Temperature on Structure and Optical Properties for ZnS nanostructure Thin Film. JOURNAL OF ADVANCES IN CHEMISTRY, 11(2), 3459–3472. https://doi.org/10.24297/jac.v11i2.6689
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