Supramolecular Hydrogen Bonded 3D Molecular Self Assembly Constructed from [(Co (nicotinamide)2(thiocyanate)2(H2O)2] Complex Showing Anti-ferromagnetic Character
DOI:
https://doi.org/10.24297/jac.v10i6.6670Keywords:
Hydrogen bonded 3D structure, spin orbital coupling.Abstract
A new three dimensional hydrogen bonded cobalt frame work from [Co(nicotinamide)2(thiocyanate)2(H2O)2] was synthesized and characterized by X-ray diffraction, magnetism ,TGA and IR spectroscopy. The compound crystallizes in Triclinic space group P-1 with a = 7.5475(19), b = 8.054(2), c =8.932(2). Alpha=73.347(4), beta=70.067(4), gamma=66.559(4) with space group P-1
Z = 1, 'C14 H16 N6 Co O4 S2', Mr =455.38, F(000) = 233 and μ(MoKα) =0.71073 mm-1. The final R = 0.0497 and wR = 0.1461 for 4185 observed reflections with I > 2σ(I) and R = 0.0721 and wR = 0.1619 for all data. X-ray diffraction analyses revealed that Co(1) is linked by the nicotinamide ligands to form the ladder shape along the c axis, which is further extended into two-dimensional networks via the joint of Co(2) along the a axis. Moreover, these two dimensional motifs are interconnected by the thiocyanate S...H bridges to form a complicated 3-D polymeric framework. The magnetic susceptibility data at 1000Oe external field in the temperature range 2-300 K obeys the Curie-Weiss law, giving θ = -24.12 K and C =2.43 thus indicating a dominant strong antiferromagnetic interaction and/or spin orbital coupling between the Co (II) ions.
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References
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[4] Juan C.M.R. and . Lee, B. Coord. Chem. Rev. 183(1999)43. (b) Tse, M.C., Cheung, K. K., Chan, M.C., and Che, C.M., Chem. Commun.(1998)3245; (c) Tadokoro, M., Isobe K., H. Uekusa, Y. Ohashi, J. Toyoda, K. Tashiro and K. Nakasujhi, Angew. Chem. Int. Ed., 1999, 38, 95; (d) G. R. Desiraju, Angew Chem., Int. Ed. Engl., 1995, 34, 2311; (e) D. F. Sun, R. Cao,Y. Q. Sun, X. Li, W. H. Bi, M. C. Hong and Y. J. Zhao, Eur.J. Inorg.Chem., (2003) 94; (f) M. L.Tong, H. K. Lee, X. M. Chen,R. B. Huang and Mak, T.C.W. J. Chem. Soc., Dalton Trans.(1999)3657.
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[8] Sailaja, S., Reddy, K., Rajasekharan, R M.V., Hureau, C., Riviere, E., Cano, J., Inorg. Chem. 42 (2003) 180. .
[9] Dey, S.K., Mondal, N., El Fallah, M.S., Vicente, R., Escuer, A., Solans, X., Font-Bardia, M., Matsushita, T. V.,Mitra, Gramlich S., Inorg. Chem. 43 (2004) 2427.
C= 1.66 emu/molΘ = -24.8
[10] Blake, A. J., Hill, S. Y., Hubberstey, P., Rectangular grid two-dimensional sheets of copper (II) bridged by both co-ordinated and hydrogen bonded 4,4_-bipyridine(4,4_-bipy) in {[Cu(-4,4_-bipy)(H2O)2][BF4]2}4,4-bipy), J. Chem. Soc. Dalton Trans. (1997) 913-914.
[11] Li, M. X., Xie, G. Y., Gu, Y. D., Synthesis, characterization and magnetic properties of one-dimensional 4,4_-bipyridinebridged manganese (II) complex: crystal structure of [Mn(-4,4_-bipy)(4,4_-bipy)(NCS)2(H2O)2]n, Polyhedron, 1995, 14:1235_1239.
[12] Tong, M.L., Chen, X.M., Yu, X.L., A novel two-dimensional rectangular network, Synthesis and structure of {[Cu(4,4_-bpy)(pyz)(H2O)2][PF6]2}n (4,4_-bpy = 4,4_-bipyridine, pyz = pyrazine), J. Chem. Soc. Dalton Trans., (1998) 5-6.
[13] Mitwa, Y., Mizuno, T., Tsuchiya, K.,Taga, T., Iwata, Y., Experimental charge density and electrostatic potential in nicotinamide ,Acta Crystallogr Acta Crystallogr. B 55(1999) 78–84.
[14] Vogalsanger B., Brown, R. D., Godfrey, P. D., and Pierlot, A. P., J. Mol. Spectrosc. 145 (1991) 1.
[15] Purcell, P. J. Phys. Chem., 68 (1964) 2666.
[16] Purcell, P. and Siger, A.J. J. Phys. Chem., 69 (1965) 4097.
[17] Pandey, Deepanjali, Narvi, S. Shahid, Mehrotra, K. Gopal, and Butcher J. Raymond, Diaquabis(Nicotinamide-Ò¡N1) bis (Thiocyanato-Ò¡S)Nickel(II) Acta Cryst. (2014). E70, m183
[18] Sheldrick, M. G.; SHELX97. Programs for Crystal Structure Analysis (Release 97-2). University of Göttingen, Germany. (1997).
[19] Wilson, C. J. A.; Ed., International Tables for Crystallography, Volume C, Kluwer Academic Publishers, Dordrecht, The Netherlands, (1995).
[20] SAINT: Area-Detector Integration Software. Siemens Industrial Automation, Inc.: Madison, WI. (1995).
[21] SADABS: Area-Detector Absorption Correction Siemens Industrial Automation, Inc.: Madison, WI. (1996).
[22] Sabbani, Supriya, Das, Samark. A simple coordination complex exhibiting colour change on slight structural modification: Synthesis and crystal structures of violet and yellow forms of [NiII(opda)2(NCS)2] (opda = orthophenylenediamine).J. Chem. Sci., Vol. 122, No. 5, September 2010, pp. 731–737. [23] Bailey, R. A., Kozak, S. L., Michelsen, T.W., Mills, W.N., Coord. Chem. Rev. 6(1971)407-445.
[24] Tramer, A.C.R. Acad. Sei. 250 (1960) 3150-3153.
[25] Nesterova, O. V., Petrusenko, S. P., Kokozay, V. N.,Skelton, B.W., Inorg. Chem.Commun. 7 (2004) 450.
[26] Du, Miao.Li, Cheng-Peng.; Guo, Jian-Hua. Inorganica Chimica Acta. 359 (2006) 2575–2582.
[27] Dubler, E., Haring, U. K., Scheller, K. H., Baltzer, P., Sigel, H., Inorg.Chem. 23, (1984)3785.
[28] Marshall, S. R., Incarvito, C. D., Manson, J. L. et al., Synthesis, structure and magnetic properties of Co2{[N(CN)2]4bpym}_H2O andM{[N(CN)2]2bpym}_H2O (M = Mn, Fe, Co; bpym = 2,2_-bipyrimidine), Inorg. Chem.39(2000) 1969-1973.
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Published
2014-10-05
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Pandey, D., S.Narvi, S., & Chaudhuri, S. (2014). Supramolecular Hydrogen Bonded 3D Molecular Self Assembly Constructed from [(Co (nicotinamide)2(thiocyanate)2(H2O)2] Complex Showing Anti-ferromagnetic Character. JOURNAL OF ADVANCES IN CHEMISTRY, 10(6), 2864–2874. https://doi.org/10.24297/jac.v10i6.6670
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