Removal of Chromium (VI) cation metal using Poly (N-vinyl-2-pyrrolidone)/Magnetite nanocomposite from aqueous media
DOI:
https://doi.org/10.24297/jac.v13i10.5825Keywords:
cation metal, N-vinyl-2-pyrrolidoneAbstract
Groundwater contamination with heavy metals is considered as serious environmental hazard that affect the human society. Nano adsorbents incorporating magnetite nanoparticles provides promising alternative to facilitate removal of heavy metal ions from wastewater. The present work focuses on removal of chromium (VI) cationic metals from aqueous media using Polyvinyl Pyrrolidone (PVP)/Magnetite (Fe3O4) Nanocomposite (MNC). Magnetite nanoparticles are synthesized using chemical co-precipitation and grafted using polyvinyl pyrrolidone to form a magnetite nanocomposite. MNC were characterized with X-ray diffraction (XRD) and Infrared absorption spectrum (FT-IR) studies to affirm the formation and presence of polymeric functional groups of PVP/Magnetite nanocomposite. Batch experiments are carried out at exclusive concentration intervals to study about the adsorption efficiency of MNC on chromium (VI) cationic metal using U-Vis spectroscopy. The results obtained through adsorption studies shows the synthesized PVP/Magnetite nanocomposites has a removal efficiency of 94%.
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References
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28. Pawinee Theamdee, Rakchart Traiphol, Boonjira Rutnakornpituk, Uthai Wichai, Metha Rutnakornpituk: Surface modification of magnetite nanoparticle with azobenzene-containing water dispersible polymer.J Nanopart Res, 13,4463-4477(2011).
29. Yongji Zhang, Hui Juan Chi, Wen Hui Zhang, Youyi Sun, Qing Liang, YuGu, Riya Jing: Highly Efficient Adsorption of Copper Ions by a PVP-Reduced Graphene Oxide Based On a New Adsorptions Mechanism. Nano-Micro Lett., 6, 80-87(2014).
30. Yanming Wang, Daji Shang and Zhongwei Niu: Removal of Heavy Metals by Poly(Vinyl Pyrrolidone)/Laponite Nanocomposite Hydrogels. Advanced Materials Research, 63-632.pp 291-297(2013).
31. Shalini Rajput, Charles U. Pittman Jr., Dinesh Mohan: Journal of Colloid and Interface Science, 468, pp. 334–346, (2016).
32. Tiffany Marin, Paula Montoya, Oscar Arnache and Jorge A. Calderon: Influence of Surface Treatment on Magnetic Properties of FeO Nanoparticles Synthesized by Electrochemical Method.J. Phys. Chem. B (2016)
33. Md. Juned, K, Ahmed, Ahmaruzzaman, M: A review on potential usage of industrial waste materials for binding heavy metal ions from aqueous solutions. Journal of Water Process Engineering,10 , pp. 39–47(2016).
34. Lakshmi Prasanna Lingamdinne, Janardhan Reddy Koduru, Yu-Lim Choi, Yoon-Young Chang, Jae-Kyu Yang: Studies on removal of Pb(II) and Cr(III) using graphene oxide based inverse spinel nickel ferrite nano-composite as sorbent. Hydrometallurgy(2015).
35. Susmita Sen Gupta, Krishna G. Bhattacharyya: Kinetics of adsorption of metal ions on inorganic materials: A review.Advances in Colloid and Interface Science,162 , pp. 39–58(2011).
36. Jiwon Lee, Tetsuhiko Isobe, Mamoru Senna: Magnetic properties of ultrafine magnetite particles and their slurries prepared via in-situ precipitation. Colloids and Surfaces,109 , pp. 121-127(1996).
37. Dhruv Mehta, Siddharth Mazumdar, S.K. Singh: Magnetic adsorbents for the treatment ofwater/wastewater—A review.Journal of Water Process Engineering,7 , pp.244–265(2015).
38. Sarita Kango, Susheel Kalia, Annamaria Cell, James Njuguna, Youssef Habibi, Rajesh Kumar: Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites—A review. Progress in Polymer Science, 2013, 778.
39. Zhihuiai, Yingcheng, Lizhizhang and Jianrongqiu: fficient Removal of Cr(VI) from Aqueous Solution with Fe@Fe2O3 Core- Shell Nanowires.Environ. Sci. Technol.42, pp.6955–6960(2008).
40. Abir Ghosh, Madhubonti Pal, Krishna Biswas, Uday Chand Ghosh, Biswaranjan Manna: Manganese oxide incorporated ferric oxide nanocomposites (MIFN): A novel adsorbent for effective removal of Cr(VI) from contaminated water. Journal of Water Process Engineering, 7, pp.176–186(2015).
41. Jong-Hee Kim; Sang-Mun Kim, Yong-II Kim: Properties of Magnetic Nanoparticles Prepared by Co-Precipitation.Journal of Nanoscience and Nanotechnology, 14, 8739–8744(2014).
42. Jing Hu, Guohua Chen, Irene M.C. Lo: Removal and recovery of Cr(VI) from wastewater by maghemite nanoparticles. Water Research, 39, 4528–4536(2005)
2. Yongchao Li, Zhaohui Jin, Tielong Li, Zongming Xiu, Yongchao Li, Zhaohui Jin, Tielong Li, Zongming Xiu, Science of the Total Environment: One-step synthesis and characterization of core–shell Fe@SiO2 nanocomposite for Cr(VI) reduction. 421-422.pp.260–266 (2012).
3. Robertm.powell, Robert w.puls, Sharon k. hightower, David a. Sabatini:Environ. Sci. Techno/. 29, pp.1913-1922(1995).
4. Md. Juned .K.Ahmed, Ahmaruzzaman,M.: A review on potential usage of industrial waste materials for binding heavy metal ions from aqueous solution. Journal of Water Process Engineering,10, pp 39-47(2016)
5. Chunming Su: Environmental implications and applications of engineered nanoscale magnetite and its hybrid nanocomposites: A review of recent literature. J.Haz.Mat. pp 0304-3894(2016).
6. Peng Yuan, Mingde Fan, Dan Yang, Hong ping He, Dong Liu, Aihua Yuan, JianXi Zhu, TianHu Chen: Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr(VI)] from aqueous solutions.J.Hazardous Materials,166, pp.821-829 (2009).
7. S.Vikram, M.Dhakshnamoorthy, R. Vasanthakumari, A. R. Rajamani, Murali Rangarajan, and Takuya Tsuzuki.: Tuning the Magnetic Properties of Iron Oxide Nanoparticles by a Room-Temperature Air-Atmosphere (RTAA) Co-Precipitation Method. J. of nanoscience and nanotechnology, 15, 3870–3878(2015).
8. T. Karthikeyan, S. Rajgopal, Lima Rose Miranda: Chromium(VI) adsorption from aqueous solution by Hevea Brasilinesis sawdust activated carbon. hazardous materials, 124,192–199(2005).
9. Audrey-Flore Ngomsik, Agnes Bee, Micheline Draye, Gerard Cote, Valerie Cabuil: Magnetic nano- and microparticles for metal removal and environmental applications: a review chimie, 8, 963-970(2005)
10. Inigo Larraza, Mar Lopez-Gonzalez, Teresa Corrales, Gema Marcelo: Hybrid materials: Magnetite–Polyethylenimine–Montmorillonite, as magnetic adsorbents for Cr(VI) water treatment. Colloids and interface science, 385, pp 24-33(2012).
11. Klausp. Raven, Amitajain, Andrichardh. Loeppert: Arsenite and Arsenate Adsorption on Ferrihydrite: Kinetics, Equilibrium, and Adsorption Envelopes. Environ. Sci. Technol., 32, 344-349(1998).
12. Neha Gupta, Atul K. Kushwaha, Chattopadhyaya.M,C.: Adsorptive removal of Pb2+, Co2+ and Ni2+ by hydroxyapatite/chitosan composite from aqueous solution.Journal of the Taiwan Institute of Chemical Engineers, 43,pp.125–131(2012).
13. Guoliang Li, Zongshan Zhao, Jiyan Liu, Guibin Jiang: Effective heavy metal removal from aqueous systems by thiol functionalized magnetic mesoporous silica .Journal of Hazardous Materials, 192, pp.277– 283(, 2011).
14. Rupali Rakhunde, Leena Deshpande, Juneja, H, D.: Chemical Speciation of Chromium in Water: A Review. Critical Reviews in Environmental Science and Technology, 42, 776–810 (2012).
15. Wei Wu, Quanguo He, Changzhong Jiang, Magnetic Iron Oxide Nanoparticles: Synthesis and Surface Functionalization Strategies. Nanoscale Res Lett, 3, pp.397–415(2008).
16. An-Hui Lu, Salabas, E, L, and Ferdi Schuth: Magnetic Nanoparticles: Synthesis, Protection,Functionalization, and Application. Angew. Chem. Int. Ed., 46, pp.1222 – 1244(2007)
17. Jiahua Zhu, Suying Wei, Minjiao Chen, Hongbo Gu, Sowjanya,B., Rapole; Sameer Pallavkar, Thomas C,. Ho, Jack Hopper, Zhanhu Guo: Magnetic nanocomposites for environmental remediation. Advanced Powder Technology,24 ,pp.459–467(2013).
18. Madhumita Bhaumik, Katlego Setshedi, Arjun Maity, Maurice S.Onyango: Chromium(VI) removal from water using fixed bed column of polypyrrole/Fe3O4 nanocomposite. chemical engineering journal, 110, pp.11-19(2013).
19. Wenjuan Shen, Yi Mu; Tan Xiao, Zhihui Ai: Magnetic Fe3O4–FeB nanocomposites with promoted Cr(VI) removal performance.Chemical Engineering Journal, 285, pp.57–68(2016).
20. Abu Zayed Md, Badruddoza; Zayed Bin Zakir Shawon, Md. Taifur Rahman; Kow Wei Hao, Kus Hidajat, Mohammad Shahab Uddin: Ionically modified magnetic nanomaterials for arsenic and chromium removal from water.Chemical Engineering, 255,607-615(2013).
21. Alicia E. Chavez-Guajardo, Juan C. Medina-Llamas, Luis Maqueira; Cesar A.S. Andrade, Kleber G.B. Alves, Celso P. de Melo: Efficient removal of Cr (VI) and Cu (II) ions from aqueous media by use of polypyrrole/maghemite and polyaniline/maghemite magnetic nanocomposites. chemical engineering journal, pp.826-836(2015).
22. Vaishnavi Sureshkumar, Kiruba Daniel, S, C, G., Ruckmani, K., Sivakumar, M.: Fabrication of chitosan–magnetite nanocomposite strip for chromium removal.App.nanosci, 6, 277(2016).
23. Junyang Xian, Qing Hua, Zhiquan Jiang, Yunsheng Ma, Weixin Huang: Size-Dependent Interaction of the Poly(N-vinyl-2-pyrrolidone)Capping Ligand with Pd Nanocrystals. Langmuir, 28, 6736−6741(2012)
24. Chao Luo, Zhang Tian, Bo Yang, Li Zhang, Shiqiang Yan: Manganese dioxide/iron oxide/acid oxidized multi-walled carbon nanotube magnetic nanocomposite for enhanced hexavalent chromium removal. chemical engineering journal , 234, 256-265(2013).
25. Ballav,N., Choi,H,J.Mishra,S,B, Maity,A.: Synthesis, characterization of Fe3O4 @glycine doped polypyrrole magnetic nanocomposites and their potential performance to remove toxic Cr(VI).Ind and Eng.Chem, 20,4085(2014).
26. Fereshte Keyhanian, Shahab Shariati, Mohammad Faraji, Maryam Hesabi: Magnetite nanoparticles with surface modification for removal of methyl violet from aqueous solutions. Arb.J.Chem, 9,S348(2016).
27. Tetsuya Osaka, Takuya Nakanishi, Sangaraju Shanmugam, Shintaro Takahama, Hong Zhang: Effect of surface charge of magnetite nanoparticles on their internalization into breast cancer and umbilical vein endothelial cells. Colloids and Surfaces B: Biointerfaces, 71, 325-330(2009).
28. Pawinee Theamdee, Rakchart Traiphol, Boonjira Rutnakornpituk, Uthai Wichai, Metha Rutnakornpituk: Surface modification of magnetite nanoparticle with azobenzene-containing water dispersible polymer.J Nanopart Res, 13,4463-4477(2011).
29. Yongji Zhang, Hui Juan Chi, Wen Hui Zhang, Youyi Sun, Qing Liang, YuGu, Riya Jing: Highly Efficient Adsorption of Copper Ions by a PVP-Reduced Graphene Oxide Based On a New Adsorptions Mechanism. Nano-Micro Lett., 6, 80-87(2014).
30. Yanming Wang, Daji Shang and Zhongwei Niu: Removal of Heavy Metals by Poly(Vinyl Pyrrolidone)/Laponite Nanocomposite Hydrogels. Advanced Materials Research, 63-632.pp 291-297(2013).
31. Shalini Rajput, Charles U. Pittman Jr., Dinesh Mohan: Journal of Colloid and Interface Science, 468, pp. 334–346, (2016).
32. Tiffany Marin, Paula Montoya, Oscar Arnache and Jorge A. Calderon: Influence of Surface Treatment on Magnetic Properties of FeO Nanoparticles Synthesized by Electrochemical Method.J. Phys. Chem. B (2016)
33. Md. Juned, K, Ahmed, Ahmaruzzaman, M: A review on potential usage of industrial waste materials for binding heavy metal ions from aqueous solutions. Journal of Water Process Engineering,10 , pp. 39–47(2016).
34. Lakshmi Prasanna Lingamdinne, Janardhan Reddy Koduru, Yu-Lim Choi, Yoon-Young Chang, Jae-Kyu Yang: Studies on removal of Pb(II) and Cr(III) using graphene oxide based inverse spinel nickel ferrite nano-composite as sorbent. Hydrometallurgy(2015).
35. Susmita Sen Gupta, Krishna G. Bhattacharyya: Kinetics of adsorption of metal ions on inorganic materials: A review.Advances in Colloid and Interface Science,162 , pp. 39–58(2011).
36. Jiwon Lee, Tetsuhiko Isobe, Mamoru Senna: Magnetic properties of ultrafine magnetite particles and their slurries prepared via in-situ precipitation. Colloids and Surfaces,109 , pp. 121-127(1996).
37. Dhruv Mehta, Siddharth Mazumdar, S.K. Singh: Magnetic adsorbents for the treatment ofwater/wastewater—A review.Journal of Water Process Engineering,7 , pp.244–265(2015).
38. Sarita Kango, Susheel Kalia, Annamaria Cell, James Njuguna, Youssef Habibi, Rajesh Kumar: Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites—A review. Progress in Polymer Science, 2013, 778.
39. Zhihuiai, Yingcheng, Lizhizhang and Jianrongqiu: fficient Removal of Cr(VI) from Aqueous Solution with Fe@Fe2O3 Core- Shell Nanowires.Environ. Sci. Technol.42, pp.6955–6960(2008).
40. Abir Ghosh, Madhubonti Pal, Krishna Biswas, Uday Chand Ghosh, Biswaranjan Manna: Manganese oxide incorporated ferric oxide nanocomposites (MIFN): A novel adsorbent for effective removal of Cr(VI) from contaminated water. Journal of Water Process Engineering, 7, pp.176–186(2015).
41. Jong-Hee Kim; Sang-Mun Kim, Yong-II Kim: Properties of Magnetic Nanoparticles Prepared by Co-Precipitation.Journal of Nanoscience and Nanotechnology, 14, 8739–8744(2014).
42. Jing Hu, Guohua Chen, Irene M.C. Lo: Removal and recovery of Cr(VI) from wastewater by maghemite nanoparticles. Water Research, 39, 4528–4536(2005)
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Published
2017-03-01
How to Cite
G, P., BS, S., S, R., G, R., & J, S. (2017). Removal of Chromium (VI) cation metal using Poly (N-vinyl-2-pyrrolidone)/Magnetite nanocomposite from aqueous media. JOURNAL OF ADVANCES IN CHEMISTRY, 13(10), 5886–5891. https://doi.org/10.24297/jac.v13i10.5825
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