Synthesis of Anionic Surface Active Agents Containing Heterocyclic Moiety From Long Chain Fatty Alcohols
DOI:
https://doi.org/10.24297/jac.v13i10.5819Keywords:
Heterocyclic, Anionic SurfaceAbstract
A series of novel groups of anionic surface active agent were synthesized. Synthesis of these surfactants via the reaction of long chain fatty alcohols (octyl, decyl and dodecyl) with maleic anhydride to give monoester. The monoester chloride reacted with amino derivatives of heterocyclic rings followed by addition of NaHSO3 .The surface tension, interfacial tension; Kraft point, emulsifying and wetting power were evaluated. Stability to hydrolysis, biodegradability and biological activities were measured. A comparison studies between the chemical structures and the results were done.
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2. Linfield, W.M, Anionic Surfactants, pt. 1, Marce Dekker Inc., New York (1976).
3. Gawalek, G., Tenside, Akademie Uelag, Berlin(1975).
4. Linder,k.,Tenside,Textilhilfsmittel,Waschrohstoffe,Wissenschaftlie Verlagsgesellschaft mbH , Bd 1 , Stuttgart(1964).
5. Schwartz A. M., Perry, J.W., Berch, J., Surface Active Agents and Detergents, Vol. 11, Interscience Publishers Inc., New York(1958).
6. Katritzky Comprehensive., Heterocyclic. Chem. Vol. 5 p. 56,233, 528 and 787(1984).
7. Allen,C. F. and Bell. A., Org. Synthesis, 26,11,(1946).
8. Townsend L. B., and Tipson, R. S., ''Nucleic Acid Chemistry'' Willey , New York. Part 2 and 1(1978).
9. Amine. M. S., Eissa, A.M.F., Shaaban, A. F., El-Sawy, A., and El-Sayed, R.I., Indian Journal of Chemistry Vo1. 37 B,pp. 1135-1156, 16 (1998).
10. Eissa A M F, M. El Hefnawy and M. Deef Allah , J Surfact Deterg , 16, 2, pp 161-171, 2013.
11. Findly A., Practical physical chemistry,6th edn. Longman, London, 1040-1069,1963.
12. Eissa AMF, EL-Hefnawy M, Bader S, Radwan M, Deef Allah M,
Synthesis and characterization of anionic polymeric surfactants
based on sulfonated styrene, J Surf Deterg, 15:411-418(2012).
13. El-Sukkary, M. M. A., El-Dib F., El-Sawy. A. A. and El-Ashry, S. H., Preparation of nonionic surfactants from rice bran oil,, Hungarian Journal of Industrial Chemistry, (14), 219 (1986).
14. Draves,C.Z., J.Am.Dye Stuff Reporter,20,p.p 201,1941.
15. Eter, E.T., Richard, R.E. and Darid,A., Biodegradable surfactants starch,J.Am.Oil Chem.Soc.,51,p.p.486-494,1974.
16. Eissa, A. M. F. , Grasas y Aceites., 58 (4) 379 (2007).
17. Eissa. A. M. F.; Olaj, Szappan, Kozmetika, 51 (4), 155 (2002).
18. Falbe J., Surfactants for Consumer, Chapter 4, Springer-Verlag, Heidelberg, 139-141(1986).
19. Leiferet C., S.Chidbouree, S.Hampson,S.workman, D.Sigee, H.A.Epton and .A.Harbour J.Appl.Bacterial.,78,97 ,1995.
20. Sageer Ahamad, Ghazala Imran, S. A. Ahmad and A. Hasnat oriental journal of chemistry, 2015, 31(2), 1169-1173¬
21. Pasee S, Cheerarot O, Baimark Y. Orient J Chem 2015; 31(3). 1551-1558
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Published
2017-03-04
How to Cite
Abdellattif, M., Eissa, A., & Mohamed, H. (2017). Synthesis of Anionic Surface Active Agents Containing Heterocyclic Moiety From Long Chain Fatty Alcohols. JOURNAL OF ADVANCES IN CHEMISTRY, 13(10), 5935–5943. https://doi.org/10.24297/jac.v13i10.5819
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