Novel removal of Anthracene from oil-contaminated water by synthesized modified magnetic nano-particles

Authors

  • Azadeh Torabian Faculty of the Environment, University of Tehran, 25 Ghods St., Enghelab Ave, Tehran
  • H. Ahmad Panahi Islamic Azad University, Central Tehran Branch, Payambar Complex, Shahrak-e Gharb, Tehran
  • G.R. Nabi Bidhendi University of Tehran, 25 Ghods St., Enghelab Ave, Tehran
  • N. Mehrdadi University of Tehran, 25 Ghods St., Enghelab Ave, Tehran

DOI:

https://doi.org/10.24297/jac.v10i2.5492

Keywords:

Anthracene, Magnetic nanoparticles, Kinetic study, Modification

Abstract

Novel magnetic nanoparticles (MNPs) modified with (3-mercaptopropyl)-trimethoxysilane (MPTMS), grafted with allyl glycidyl ether and coupled with beta naphthol, were prepared for removal of anthracene in aqueous solutions. The grafted MNPs were characterized by transmission electron microscopy (TEM), infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). The modified MNPs contributed to enhancement of the adsorption capacity and were prepared by co-precipitation. The modified MNPs were characterized by TEM, FT-IR and TGA and the adsorption and kinetic behavior of anthracene on the modified MNPs was examined. It was shown that the nano-adsorbent optimized adsorption capacity is at pH 7. Three kinetics models: pseudo-first-order, pseudo-second-order, and intraparticle diffusion were used to investigate the adsorption mechanism of the anthracene onto the modified MNPs. The best fit was obtained for the pseudo-second-order model. The synthesized nano adsorbent can be considered as a new method for anthracene adsorption in contaminated water with the benefit of fast removal by applying a magnetic field.

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Author Biographies

H. Ahmad Panahi, Islamic Azad University, Central Tehran Branch, Payambar Complex, Shahrak-e Gharb, Tehran

Department of Chemistry

G.R. Nabi Bidhendi, University of Tehran, 25 Ghods St., Enghelab Ave, Tehran

Faculty of the Environment

N. Mehrdadi, University of Tehran, 25 Ghods St., Enghelab Ave, Tehran

Faculty of the Environment

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Published

2014-06-22

How to Cite

Torabian, A., Panahi, H. A., Bidhendi, G. N., & Mehrdadi, N. (2014). Novel removal of Anthracene from oil-contaminated water by synthesized modified magnetic nano-particles. JOURNAL OF ADVANCES IN CHEMISTRY, 10(2), 2266–2275. https://doi.org/10.24297/jac.v10i2.5492

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Articles