Growth and Characterization of an Organic Nonlinear Optical Crystal: 1-Iodo-3-Nitrobenzene (INB)
DOI:
https://doi.org/10.24297/jac.v12i9.4218Keywords:
Organic crystal, Slow evaporation, Powder-X-ray diffraction, Nonlinear opticsAbstract
The 1-Iodo-3-Nitrobenzene crystal was grown by the slow evaporation method from ethanol solvent. The crystalline structure was identified by powder X-ray diffraction (PXRD). The presence of various functional group of the title material was examined by FTIR analysis. The UV-Vis absorption was carried out which shows the fundamental cutoff wavelength around 390 nm and there is no absorption in the entire visible region 390 nm to 1100 nm. The mechanical strength of the grown crystal was measured by Vicker’s microhardness tester. The thermal toughness of the grown crystal was observed by TGA-DTA and DSC studies. The electrical conductivity of the grown crystal is confirmed by dielectric measurement. The nonlinear optical character was assessed by Kurtz-Perry powder technique. This would propose that 1-iodo-3-nitro benzene crystal is a potentially capable in nonlinear optical applications.Downloads
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References
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2. Evans, C. Beucher, M.B. Masse, R. Nicoud, J.F. “Nonlinearity Enhancement by solid-state Proton Transfer: A new strategy for the Design of Nonlinear Optical Materialsâ€,Chem.Mater. 10 (1998), 847–854. 3. Vijayakumar, S. Srinivasan,P. Dinagaran,S. Balaji, J. “Growth and Characterization of Organic Nonlinear Optical (NLO) 1,3-dinitrobenzene single crystals by vertical Bridgman method and its prospects as electro-optic modulatorsâ€, International Journal of Applied Engineering Research. 10 (2015), 38055-38060.
4. Merz,K.“Secondary interactions in 1-iodo-3-nitrobenzene and 1-iodo-3,5-dinitrobenzeneâ€,ActaCrystallographica SectionC.59 (2003), 65-67.
5. Sangwal,K. “On the reverse indentation size effect and microhardness measurement of solidsâ€,Materials Chemistry and Physics, 28 (February 2000), 145–152.
6. Sangwal, K. “Review: Indentation size effect, indentation cracks and microhardness measurement of brittle crystalline solids – some basic concepts and trendsâ€,Cryst. Res. Technol. 44 (Oct. 2009), 1019–1037.
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8. Raziyeh, A.A. Saeid, A “Synthesis, Spectroscopy, Thermal Analysis, Magnetic Properties and Biological Activity Studies of Cu(II) and Co(II) Complexes with Schiff Base Dye Ligandsâ€, Molecules, 17 (2012), 6434-6448.
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11 (June 2004), 207-211. 11. Kurtz, S.K. Perry,T.T. “A powder technique for the evaluation of nonlinear optical materialsâ€. Journal of applied physics, 39(1968), 3798-3813.
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13. Kushwaha, S.K. Vijayan, N. Bhagavannarayana, G. “Growth by SR method and characterization of bis(thiourea)zinc(II) chloride single crystalsâ€,Materials letters, 62(2008), 3931-3933.
14. Joncher, A.K. “A new understanding of the dielectric relaxation of solidsâ€, Journal of materials science, 16 (1981) 2037-2060.
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Published
2016-11-14
How to Cite
kumar, S., Srinivasan, P., Dinagaran, S., & Balaji, J. (2016). Growth and Characterization of an Organic Nonlinear Optical Crystal: 1-Iodo-3-Nitrobenzene (INB). JOURNAL OF ADVANCES IN CHEMISTRY, 12(9), 4364–4370. https://doi.org/10.24297/jac.v12i9.4218
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