Synthesis, Crystal Structure and Characterization of [(CH3 CH2)4N] Mn1,5 Cl3 4H2O Cl 2(H2O)

Abstract

Single crystals of [(CH₃CH₂)₄N] Mn_1,5 Cl₃ 4H₂O Cl 2(H₂O) were grown by the slow evaporation technique and characterized by means of single-crystal X-ray diffraction, FT-IR and Raman spectroscopy. The title compound belongs to the triclinic space group P with the following unit cell dimensions: a =7.5425(4) Ã…, b=9.8464 Ã…, c=13.7671(6) Ã…, α=89.951(3)°,β=89.753(3)°, γ=81.861(3)°, Z=4. These structures have solved using direct methods and refined by least-squares analysis. The structure was solved by the direct method and refined to final R value of 0.0567. The projection of [(CH₃CH₂)₄N] Mn_1,5 Cl₃ 4H₂O Cl 2(H₂O) in the plan (a,b) shows an arrangement in layers perpendicular to the direction b . The structure consists of infinite parallel two-dimensional planes built connected ions and water molecules by strong O-H…O and O-H…Cl hydrogen bonding.