Synthesis and Crystal Structure of 3-3'-Diaminomethyldipropylammonium Hexachlorobismuthate (III)

Authors

  • Yosra Baklouti Faculty of Sciences of Sfax Tunisia
  • Abdelaziz Koumina ENS de Marrakech, Département de physique, Université Cadi-Ayyad Marrakech
  • Mohamed Fliyou ENS de Marrakech, Département de physique, Université Cadi-Ayyad Marrakech
  • Fatma Zouari Laboratoire des Sciences des Matériaux et d’Environnement, Faculté des Sciences de Sfax, BP 1171, 3000, Sfax

DOI:

https://doi.org/10.24297/jac.v8i1.4031

Keywords:

Organic–inorganic hybrid material, Crystal structure, Halogenobismuthates(III), Organic “inorganic hybrid material

Abstract

Synthesis and crystal structure of 3-3-diamino-N-methyldipropylammonuim hexachlorobismuthate (III) are reported. The compound crystallizes in the triclinic system with space group P1. The unit cell dimensions are: a = 7.5580(5), b =7.8710(6), c = 8.3709(7)… with Z=1. The crystal is built up of separated [BiCl6]3- octahedral anions and 3-3-diamino-N- methyldipropylammonium cations. The organic layers are arranged in sandwich between the anionic ones. The crystal packing is governed by means of the ionic N“HCl hydrogen bonds, forming a three dimensional network.

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Published

2016-12-20

How to Cite

Baklouti, Y., Koumina, A., Fliyou, M., & Zouari, F. (2016). Synthesis and Crystal Structure of 3-3’-Diaminomethyldipropylammonium Hexachlorobismuthate (III). JOURNAL OF ADVANCES IN CHEMISTRY, 8(1), 1500–1507. https://doi.org/10.24297/jac.v8i1.4031

Issue

Vol. 8 No. 1 (2014)

Section

Articles

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