Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole

Authors

  • Araceli Vega-Paz Instituto Mexicano del Petróleo (IMP) Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacan, México D.F., 07730
  • Luisa E. Montiel Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F
  • Carolina Zuriaga-Monroy Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.
  • José-Manuel Martínez-Magadán Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.
  • Jesús Marín-Cruz Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F

DOI:

https://doi.org/10.24297/jac.v7i3.2387

Keywords:

N-(α-amino-alkyl)-benzotriazole, DSC, TGA, Density Functional Theory, thermal stability

Abstract

N-(α-amino-alkyl)-benzotriazole, a derivative of Benzotriazole (BTZ), was synthesized via a Mannich reaction addition. The chemical characterization shows that when C19H32N4supramolecule is subjected to heating process the covalent bonds of aminal carbon are broken, modifying supramolecule structure, this results in a rearrangement to the structure dodecan ammonium-1-benzotriazol-1-ate, [BTZ- amine12+].Quantum chemical calculations based on DFT method were performed on the C19H32N4 molecule. The results show that in a derivative of BTZ exists a weak bond where its break may occur.

Downloads

Download data is not yet available.

Author Biographies

Araceli Vega-Paz, Instituto Mexicano del Petróleo (IMP) Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacan, México D.F., 07730

Programa de Ingeniería Molecular

Luisa E. Montiel, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F

Programa de Ingeniería Molecular

Carolina Zuriaga-Monroy, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.

Programa de Estudios de Posgrado

José-Manuel Martínez-Magadán, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F.

Programa de Recuperación de Hidrocarburos

Jesús Marín-Cruz, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacán, 07730,México D.F

Programa de Ingeniería Molecular

Downloads

Published

2011-12-17

How to Cite

Vega-Paz, A., Montiel, L. E., Zuriaga-Monroy, C., Martínez-Magadán, J.-M., & Marín-Cruz, J. (2011). Thermal stability of N-(a ±-amino-dodecyl)-benzotriazole. JOURNAL OF ADVANCES IN CHEMISTRY, 7(3), 1440–1447. https://doi.org/10.24297/jac.v7i3.2387

Issue

Vol. 7 No. 3 (2014)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.