Synthesis, Crystal structure of hepta (pyridinium) bis (hexachlorobismuthate (III)) nitrate [C5H6N]7(BiCl6)2(NO3)

Authors

  • Ben Tahar Fayçal Laboratoire des Sciences de Matériaux et de l’Environnement (MESLab), Faculté des Sciences de Sfax (FSS), Université de Sfax, Route de Soukra - km 3,5 - BP 1171, 3018- Sfax
  • Perez Olivier Laboratoire CRISMAT, UMR 6508 CNRS, ENSICAEN- 6 Boulevard du Marechal Juin- 14050- Caen- Cedex 4
  • Slaheddine Chaabouni Laboratoire des Sciences de Matériaux et de l’Environnement (MESLab), Faculté des Sciences de Sfax (FSS), Université de Sfax, Route de Soukra - km 3,5 - BP 1171, 3018- Sfax

DOI:

https://doi.org/10.24297/jac.v9i2.2353

Keywords:

Organic–inorganic hybrid material, Crystal structure, Halogenobismuthates(III)

Abstract

An hepta (pyridinium) bis (hexachlorobismuthate (III)) nitrate, (C5H6N)7(BiCl6)2(NO3) crystallizes at room temperature in the monoclinic system, space group P21/n, with the following unit-cell parameters: a = 9.555(1) Å, b = 16.847(1) Å, c = 32.522(1) Å, β = 94.37° , V = 5219.8 Å3 and four molecules per unit cell. Its crystal structure was determined and refined down to R1 = 0.0504, wR2 = 0.0667. The structure of the title compound, (C5H6N)7(BiCl6)2(NO3) consists of seven monoprotonated pyridinium (C5H6N)+ cations, two independent octahedron [BiCl6]3- and an isolated NO3- anion. These entities are linked together through N-H.....Cl and N-H.....O hydrogen bonds, originating from the (C5H6N)+ groups and the isolated anion of nitrate to forming a three dimensional network.

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Published

2013-04-07

How to Cite

Fayçal, B. T., Olivier, P., & Chaabouni, S. (2013). Synthesis, Crystal structure of hepta (pyridinium) bis (hexachlorobismuthate (III)) nitrate [C5H6N]7(BiCl6)2(NO3). JOURNAL OF ADVANCES IN CHEMISTRY, 9(2), 1975–1987. https://doi.org/10.24297/jac.v9i2.2353

Issue

Vol. 9 No. 2 (2014)

Section

Articles

License

Creative Commons License All articles published in Journal of Advances in Linguistics are licensed under a Creative Commons Attribution 4.0 International License.

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