ATTENUATION OF HEAVY METALS IN SEDIMENTS OF THE BONNY ESTUARY, NIGERIA: THE ROLE OF OXYGEN

Authors

  • Dr. Dike Henry Ogbuagu Federal University of Technology, PMB 1526, Owerri
  • Dagogo Eras Dinney Nigeria Liquefied Natural Gas Limited, Bonny

DOI:

https://doi.org/10.24297/jac.v9i1.2305

Keywords:

Bonny Estuary, sediments, anoxia, heavy metals, attenuation

Abstract

Sediments of the Bonny Estuary, which is repository to pollutants from various industrial and shipment activities in its catchment was investigated for rate of natural attenuation of toxic metals (Cd, Mn, Cr, Pb, Cu, Ni, Fe) under aerobic and anaerobic conditions. Samples were collected with pre-grab sampler from seabed, sieved in the laboratory and monitored under aerobic and anaerobic conditions. After incubation at 18°C, harvests were made on days 1, 14, 28 and 42 and levels of the metals determined spectrophotometrically. Variation plots, ANOVA, Means plots, Student’s t-test and Pearson correlation (r) were used to analyze data. Concentration reductions were higher in aerobic condition in the order Cu(15.5%)> Cd(11.4%)> Fe(8.0%)>Mn(5.7%)> Cr(4.4%)> Ni(4.2%)>Pb(3.9%) than in anaerobic condition which was in the order Cu(7.5%)> Cd(7.4%)>Pb(2.4%)>Mn/Cr(1.8% each)> Fe(0.9%)> Ni(0.5%). There was significant heterogeneity in metals reductions (Sig. F=0.000) on all the harvest days, especially of Cu, Pb and Fe at P<0.05. Attenuation of Mn also differed markedly between the aerobic and anaerobic conditions (Sig. t=0.005) at the 95% confidence interval. pH influenced the attenuation of Ni (r=0.766) and Fe (r=0.795) (P<0.05) as well as Cd (r=0.968), Cr (r=0.861), Pb (r=0.989) and Cu (r=0.950) (P<0.01). Results indicate that rate of attenuation was slow and slightly enhanced by oxygenation.

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Author Biography

Dr. Dike Henry Ogbuagu, Federal University of Technology, PMB 1526, Owerri

Department of Environmental Technology

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Published

2013-01-01

How to Cite

Ogbuagu, D. D. H., & Dinney, D. E. (2013). ATTENUATION OF HEAVY METALS IN SEDIMENTS OF THE BONNY ESTUARY, NIGERIA: THE ROLE OF OXYGEN. JOURNAL OF ADVANCES IN CHEMISTRY, 9(1), 1810–1821. https://doi.org/10.24297/jac.v9i1.2305

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