Spectroscopic Investiqation Complex Formation Of Vanadium Using 2,6-Dithiol-4-Methylphenol And HudrophobAmins
DOI:
https://doi.org/10.24297/jac.v11i4.2208Keywords:
Extraction-spectrophotometric method, vanadium, 2, 6-dithiol-4-methylphenol (DTMP), hydrofob amins (Am), mixed-ligand complexes.Abstract
Mixed-ligand complexes of Vanadium (IV, V) with 2,6-dithiol-4-methylphenol (DTMP) and hydrofobamins(Am) have been studied by spectrophotometry. Extraction of mixed ligand complexes is maximal at pH 3.8-5.3. The optimal conditions for the formation and extraction of mixed-ligand compounds have been found and the ratios of components I the complexes have been determined. The Beer’s law was applicable in the range of 0.04-3.6mg/ml.The method is free from common interferences. A procedure has been developed for extraction – spectro-photometric determination vanadium in soils andin oil and oil-products.
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